(1S)-(-)-10-(N,N-dicyclohexylsulfonamide) isoborneyl vinyl ether

Base Information

• Chemical Name: (1S)-(-)-10-(N,N-dicyclohexylsulfonamide) isoborneyl vinyl ether
• CAS No.: 351464-38-5
• Molecular Formula: C₂₄H₄₁NO₃S
• Molecular Weight: 423.66
• Mol file: 351464-38-5.mol

Synonyms:(1S)-(-)-10-(N,N-dicyclohexylsulfonamide) isoborneyl vinyl ether

Chemical Property of (1S)-(-)-10-(N,N-dicyclohexylsulfonamide) isoborneyl vinyl ether

Chemical Property:

Purity/Quality:

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Technology Process of (1S)-(-)-10-(N,N-dicyclohexylsulfonamide) isoborneyl vinyl ether

There total 1 articles about (1S)-(-)-10-(N,N-dicyclohexylsulfonamide) isoborneyl vinyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

-butyl vinyl ether (111-34-2,92680-80-3) + (-)-10-dicyclohexylsulfamoyl-D-isoborneol (96303-88-7) → (1S)-(-)-10-(N,N-dicyclohexylsulfonamide) isoborneyl vinyl ether (351464-38-5)

Guidance literature:

With mercury(II) diacetate; at 120 ℃; for 15h;

DOI:10.1021/jo010182v

Reference yield: 85.0%

(2E)-3-phenyl-2-nitroprop-2-enenitrile (38436-36-1,37630-63-0) + (1S)-(-)-10-(N,N-dicyclohexylsulfonamide) isoborneyl vinyl ether (351464-38-5) → (4R,6R)-trans-6-[(1S)-10-(N,N-dicyclohexylsulfonamide)isoborneyl]-4-phenyl-5,6-dihydro-4H-1,2-oxazine-3-carbonitrile 2-oxide + (4R,6S)-cis-6-[(1S)-10-(N,N-dicyclohexylsulfonamide)isoborneyl]-4-phenyl-5,6-dihydro-4H-1,2-oxazine-3-carbonitrile 2-oxide

Guidance literature:

In water; at 20 ℃; for 1h;

DOI:10.1021/jo010182v

Reference yield: 80.0%

(E)-1-cyano-2-(4'-methoxyphenyl)-1-nitroethene (57222-08-9,37630-64-1) + (1S)-(-)-10-(N,N-dicyclohexylsulfonamide) isoborneyl vinyl ether (351464-38-5) → C-{2-[3-cyano-4-(4-methoxy-phenyl)-2-oxy-5,6-dihydro-4H-[1,2]oxazin-6-yloxy]-7,7-dimethyl-bicyclo[2.2.1]hept-1-yl}-N,N-dicyclohexyl-methanesulfonamide + (4R,6S)-cis-6-[(1S)-10-(N,N-dicyclohexylsulfonamide)isoborneyl]-4-(4-methoxyphenyl)-5,6-dihydro-4H-1,2-oxazine-3-carbonitrile 2-oxide

Guidance literature:

In water; at 20 ℃; for 1h;

DOI:10.1021/jo010182v

upstream raw materials:

-butyl vinyl ether

(-)-10-dicyclohexylsulfamoyl-D-isoborneol