(+/-)-phyllanthocin

Base Information

Chemical Name:(+/-)-phyllanthocin
CAS No.:131102-87-9
Molecular Formula:C₂₅H₃₀O₇
Molecular Weight:442.509
Hs Code.:

Synonyms:(+/-)-phyllanthocin

Suppliers and Price of (+/-)-phyllanthocin

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (+/-)-phyllanthocin

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of (+/-)-phyllanthocin

There total 34 articles about (+/-)-phyllanthocin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 131103-11-2
C₁₆H₂₄O₆

: 102-92-1,17082-09-6
Cinnamoyl chloride

: 131102-87-9
(+/-)-phyllanthocin

Guidance literature:: With dmap; In dichloromethane;
DOI:10.1016/S0040-4020(97)01016-8

Reference yield:

: 124-41-4
sodium methylate

: 63166-73-4,134357-80-5
phyllanthoside

: 62948-37-2,131102-87-9
phyllanthocin

: 16741-34-7,73246-48-7,74410-56-3,88547-61-9,88548-11-2,123878-16-0,130009-30-2,130009-31-3,130856-80-3,130856-81-4,134357-73-6,148152-56-1
phyllanthose

Guidance literature:: In methanol;
DOI:10.1139/v82-141

Reference yield:

: 29943-42-8,143562-54-3
Tetrahydro-4H-pyran-4-one

: 131102-87-9
(+/-)-phyllanthocin

Guidance literature:: Multi-step reaction with 15 steps

1: 100 percent / p-TsOH*H₂O / benzene / 1 h / Heating

2: 91 percent / pyridinium bromide perbromide / tetrahydrofuran / 0.25 h / Ambient temperature

3: 77 percent / t-BuOK / dimethylsulfoxide / 0.25 h / Ambient temperature

4: 1.) t-BuLi, 2.) HMPA / 1.) THF, pentane, 0 deg C, 1 h, 2.) THF, pentane, -78 deg C, 30 min

5: oxalic acid / CH₂Cl₂ / 2 h / Ambient temperature

6: (COCl)2, DMSO / CH₂Cl₂ / 0.5 h / -78 °C

7: ZnBr₂ / CH₂Cl₂ / 23 h / Ambient temperature

8: camphorsulfonic acid (CSA) / benzene / 18 h / Ambient temperature

9: 79 percent / dimethylsulfoxide; tetrahydrofuran / 1.75 h / 0 - 20 °C

10: 217 mg / H₂ / 10percent Pd/C / methanol / 0.75 h / Ambient temperature

11: NaIO₄, RuO₂ / H₂O; CCl₄; acetonitrile / 1.5 h / 0 - 20 °C

12: diethyl ether / 0 °C

14: 82 percent / NaBH₄ / methanol; tetrahydrofuran / 0.5 h / -20 °C

15: 74 percent / 4-(N,N-dimethylamino)pyridine (DMAP) / pyridine / 26 h / Ambient temperature

With N,N,N,N,N,N-hexamethylphosphoric triamide; dmap; ruthenium(IV) oxide; sodium tetrahydroborate; sodium periodate; oxalyl dichloride; camphor-10-sulfonic acid; potassium tert-butylate; hydrogen; tert.-butyl lithium; pyridinium hydrobromide perbromide; oxalic acid; toluene-4-sulfonic acid; dimethyl sulfoxide; zinc dibromide; palladium on activated charcoal; In tetrahydrofuran; pyridine; methanol; tetrachloromethane; diethyl ether; dichloromethane; water; dimethyl sulfoxide; acetonitrile; benzene;