bis(1,1-dimethylethyl) 2,2'-{4-{[3,5-bis(hydroxymethyl)phenoxy]methyl}-1,3-phenylenebis(oxy)}bis[acetate]

Base Information

Chemical Name:bis(1,1-dimethylethyl) 2,2'-{4-{[3,5-bis(hydroxymethyl)phenoxy]methyl}-1,3-phenylenebis(oxy)}bis[acetate]
CAS No.:434929-06-3
Molecular Formula:C₂₇H₃₆O₉
Molecular Weight:504.577
Hs Code.:

Synonyms:bis(1,1-dimethylethyl) 2,2'-{4-{[3,5-bis(hydroxymethyl)phenoxy]methyl}-1,3-phenylenebis(oxy)}bis[acetate]

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Chemical Property of bis(1,1-dimethylethyl) 2,2'-{4-{[3,5-bis(hydroxymethyl)phenoxy]methyl}-1,3-phenylenebis(oxy)}bis[acetate]

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Technology Process of bis(1,1-dimethylethyl) 2,2'-{4-{[3,5-bis(hydroxymethyl)phenoxy]methyl}-1,3-phenylenebis(oxy)}bis[acetate]

There total 3 articles about bis(1,1-dimethylethyl) 2,2'-{4-{[3,5-bis(hydroxymethyl)phenoxy]methyl}-1,3-phenylenebis(oxy)}bis[acetate] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 153707-56-3
3,5-bis(hydroxymethyl)phenol

: 267874-29-3
bis(1,1-dimethylethyl) 2,2'-[4-(bromomethyl)-1,3-phenylenebis(oxy)]bis[acetate]

: 434929-06-3
bis(1,1-dimethylethyl) 2,2'-{4-{[3,5-bis(hydroxymethyl)phenoxy]methyl}-1,3-phenylenebis(oxy)}bis[acetate]

Guidance literature:: With 18-crown-6 ether; potassium carbonate; In acetone; for 12h; Heating;
DOI:10.1002/1522-2675(200201)85:1<288::AID-HLCA288>3.0.CO;2-I

Reference yield:

: 13036-02-7
Dimethyl 5-hydroxyisophthalate

: 434929-06-3
bis(1,1-dimethylethyl) 2,2'-{4-{[3,5-bis(hydroxymethyl)phenoxy]methyl}-1,3-phenylenebis(oxy)}bis[acetate]

Guidance literature:: Multi-step reaction with 2 steps

1: 84 percent / LiAlH₄ / tetrahydrofuran / 4 h / 0 - 20 °C

2: 88 percent / K₂CO₃; [18]crown-6 / acetone / 12 h / Heating

With lithium aluminium tetrahydride; 18-crown-6 ether; potassium carbonate; In tetrahydrofuran; acetone;
DOI:10.1002/1522-2675(200201)85:1<288::AID-HLCA288>3.0.CO;2-I

Reference yield:

: 200133-25-1
(3-tert-butoxycarbonylmethoxy-5-hydroxymethylphenoxy)acetic acid tert-butyl ester

: 434929-06-3
bis(1,1-dimethylethyl) 2,2'-{4-{[3,5-bis(hydroxymethyl)phenoxy]methyl}-1,3-phenylenebis(oxy)}bis[acetate]

Guidance literature:: Multi-step reaction with 2 steps

1: 73 percent / PPh₃; CBr₄ / tetrahydrofuran / 3 h / 0 °C

2: 88 percent / K₂CO₃; [18]crown-6 / acetone / 12 h / Heating

With 18-crown-6 ether; carbon tetrabromide; potassium carbonate; triphenylphosphine; In tetrahydrofuran; acetone;
DOI:10.1002/1522-2675(200201)85:1<288::AID-HLCA288>3.0.CO;2-I