(R)-[2-(S-(3,5-dimethylphenyl)-S-methylsulfoximinoyl)phenyl](diphenyl)phosphinoxide

Base Information

Chemical Name:(R)-[2-(S-(3,5-dimethylphenyl)-S-methylsulfoximinoyl)phenyl](diphenyl)phosphinoxide
CAS No.:875296-35-8
Molecular Formula:C₂₇H₂₆NO₂PS
Molecular Weight:459.549
Hs Code.:

Synonyms:(R)-[2-(S-(3,5-dimethylphenyl)-S-methylsulfoximinoyl)phenyl](diphenyl)phosphinoxide

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Chemical Property of (R)-[2-(S-(3,5-dimethylphenyl)-S-methylsulfoximinoyl)phenyl](diphenyl)phosphinoxide

Chemical Property:

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Technology Process of (R)-[2-(S-(3,5-dimethylphenyl)-S-methylsulfoximinoyl)phenyl](diphenyl)phosphinoxide

There total 3 articles about (R)-[2-(S-(3,5-dimethylphenyl)-S-methylsulfoximinoyl)phenyl](diphenyl)phosphinoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 875296-30-3
(R)-S-methyl-S-(3,5-dimethylphenyl)sulfoximine

: 88652-74-8
(2-bromophenyl)diphenylphosphine oxide

: 875296-35-8
(R)-[2-(S-(3,5-dimethylphenyl)-S-methylsulfoximinoyl)phenyl](diphenyl)phosphinoxide

Guidance literature:: With copper(l) iodide; cesium acetate; In dimethyl sulfoxide; at 90 ℃;
DOI:10.1002/anie.200502482

Reference yield:

: C₁₁H₁₂F₃NO₂S

: 875296-35-8
(R)-[2-(S-(3,5-dimethylphenyl)-S-methylsulfoximinoyl)phenyl](diphenyl)phosphinoxide

Guidance literature:: Multi-step reaction with 2 steps

1: 1.6 g / K₂CO₃ / methanol / 2 h / 20 °C

2: 74 percent / CsOAc; CuI / dimethylsulfoxide / 90 °C

With copper(l) iodide; cesium acetate; potassium carbonate; In methanol; dimethyl sulfoxide;
DOI:10.1002/anie.200502482

Reference yield:

: 197718-55-1
(R)-(3,5-dimethylphenyl)(methyl)sulfoxide

: 875296-35-8
(R)-[2-(S-(3,5-dimethylphenyl)-S-methylsulfoximinoyl)phenyl](diphenyl)phosphinoxide

Guidance literature:: Multi-step reaction with 3 steps

1: MgO; [Rh₂(OAc)4]; PhI(OAc)2 / CH₂Cl₂ / 24 h / 20 °C

2: 1.6 g / K₂CO₃ / methanol / 2 h / 20 °C

3: 74 percent / CsOAc; CuI / dimethylsulfoxide / 90 °C

With dirhodium tetraacetate; copper(l) iodide; [bis(acetoxy)iodo]benzene; cesium acetate; magnesium oxide; potassium carbonate; In methanol; dichloromethane; dimethyl sulfoxide;
DOI:10.1002/anie.200502482