(5S,6R)-3,3,8,8-tetraisopropyl-5-[(R)-2-(4-methoxybenzyloxy)nonyl]-2,9-dimethyl-6-vinyl-4,7-dioxa-3,8-disiladecane

Base Information

Chemical Name:(5S,6R)-3,3,8,8-tetraisopropyl-5-[(R)-2-(4-methoxybenzyloxy)nonyl]-2,9-dimethyl-6-vinyl-4,7-dioxa-3,8-disiladecane
CAS No.:1353889-17-4
Molecular Formula:C₃₉H₇₄O₄Si₂
Molecular Weight:663.185
Hs Code.:

Synonyms:(5S,6R)-3,3,8,8-tetraisopropyl-5-[(R)-2-(4-methoxybenzyloxy)nonyl]-2,9-dimethyl-6-vinyl-4,7-dioxa-3,8-disiladecane

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Chemical Property of (5S,6R)-3,3,8,8-tetraisopropyl-5-[(R)-2-(4-methoxybenzyloxy)nonyl]-2,9-dimethyl-6-vinyl-4,7-dioxa-3,8-disiladecane

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Technology Process of (5S,6R)-3,3,8,8-tetraisopropyl-5-[(R)-2-(4-methoxybenzyloxy)nonyl]-2,9-dimethyl-6-vinyl-4,7-dioxa-3,8-disiladecane

There total 10 articles about (5S,6R)-3,3,8,8-tetraisopropyl-5-[(R)-2-(4-methoxybenzyloxy)nonyl]-2,9-dimethyl-6-vinyl-4,7-dioxa-3,8-disiladecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 1353889-16-3
(3R,4S,6R)-6-(4-methoxybenzyloxy)-2-(triisopropylsilyloxy)tridec-1-en-3-ol

: 80522-42-5
triisopropylsilyl trifluoromethanesulfonate

: 1353889-17-4
(5S,6R)-3,3,8,8-tetraisopropyl-5-[(R)-2-(4-methoxybenzyloxy)nonyl]-2,9-dimethyl-6-vinyl-4,7-dioxa-3,8-disiladecane

Guidance literature:: With 2,6-dimethylpyridine; In dichloromethane; at 0 ℃; for 0.5h;
DOI:10.1055/s-0030-1260174

Reference yield:

: 1353889-12-9
(2S,4S,E)-1-(tert-butyldimethylsilyloxy)-2-(triisopropylsilyloxy)undec-5-en-4-ol

: 1353889-17-4
(5S,6R)-3,3,8,8-tetraisopropyl-5-[(R)-2-(4-methoxybenzyloxy)nonyl]-2,9-dimethyl-6-vinyl-4,7-dioxa-3,8-disiladecane

Guidance literature:: Multi-step reaction with 6 steps

1: platinum(IV) oxide; hydrogen / ethyl acetate / 2 h

2: copper(II) bis(trifluoromethanesulfonate) / toluene / 12 h / Inert atmosphere

3: camphor-10-sulfonic acid / methanol; dichloromethane / 0.5 h / 0 °C / Inert atmosphere

4: 2-(iodoxy)benzoic acid; dimethyl sulfoxide / dichloromethane / 2 h / 20 °C

5: tetrahydrofuran / 0.17 h / -78 °C

6: 2,6-dimethylpyridine / dichloromethane / 0.5 h / 0 °C

With 2,6-dimethylpyridine; platinum(IV) oxide; 2-(iodoxy)benzoic acid; camphor-10-sulfonic acid; hydrogen; copper(II) bis(trifluoromethanesulfonate); dimethyl sulfoxide; In tetrahydrofuran; methanol; dichloromethane; ethyl acetate; toluene;
DOI:10.1055/s-0030-1260174

Reference yield:

: 1353889-20-9
C₂₈H₅₀O₄Si

: 1353889-17-4
(5S,6R)-3,3,8,8-tetraisopropyl-5-[(R)-2-(4-methoxybenzyloxy)nonyl]-2,9-dimethyl-6-vinyl-4,7-dioxa-3,8-disiladecane

Guidance literature:: Multi-step reaction with 2 steps

1: tetrahydrofuran / 0.17 h / -78 °C

2: 2,6-dimethylpyridine / dichloromethane / 0.5 h / 0 °C

With 2,6-dimethylpyridine; In tetrahydrofuran; dichloromethane;
DOI:10.1055/s-0030-1260174