(3aS,4S,6S,6aR)-4-Benzyloxymethyl-6-(4-methoxy-benzyloxy)-4-methyl-tetrahydro-cyclopenta[1,3,2]dioxathiole 2,2-dioxide

Base Information

Chemical Name:(3aS,4S,6S,6aR)-4-Benzyloxymethyl-6-(4-methoxy-benzyloxy)-4-methyl-tetrahydro-cyclopenta[1,3,2]dioxathiole 2,2-dioxide
CAS No.:247589-92-0
Molecular Formula:C₂₂H₂₆O₇S
Molecular Weight:434.51
Hs Code.:

Synonyms:(3aS,4S,6S,6aR)-4-Benzyloxymethyl-6-(4-methoxy-benzyloxy)-4-methyl-tetrahydro-cyclopenta[1,3,2]dioxathiole 2,2-dioxide

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Chemical Property of (3aS,4S,6S,6aR)-4-Benzyloxymethyl-6-(4-methoxy-benzyloxy)-4-methyl-tetrahydro-cyclopenta[1,3,2]dioxathiole 2,2-dioxide

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Technology Process of (3aS,4S,6S,6aR)-4-Benzyloxymethyl-6-(4-methoxy-benzyloxy)-4-methyl-tetrahydro-cyclopenta[1,3,2]dioxathiole 2,2-dioxide

There total 2 articles about (3aS,4S,6S,6aR)-4-Benzyloxymethyl-6-(4-methoxy-benzyloxy)-4-methyl-tetrahydro-cyclopenta[1,3,2]dioxathiole 2,2-dioxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: (3aS,4S,6S,6aR)-4-Benzyloxymethyl-6-(4-methoxy-benzyloxy)-4-methyl-tetrahydro-cyclopenta[1,3,2]dioxathiole 2-oxide

: 247589-92-0
(3aS,4S,6S,6aR)-4-Benzyloxymethyl-6-(4-methoxy-benzyloxy)-4-methyl-tetrahydro-cyclopenta[1,3,2]dioxathiole 2,2-dioxide

Guidance literature:: With ruthenium trichloride; sodium periodate; water; In tetrachloromethane; acetonitrile;
DOI:10.1039/a903160j

Reference yield:

: (3S,5S)-3-Benzyloxymethyl-5-(4-methoxy-benzyloxy)-3-methyl-cyclopentane-1,2-diol

: 247589-92-0
(3aS,4S,6S,6aR)-4-Benzyloxymethyl-6-(4-methoxy-benzyloxy)-4-methyl-tetrahydro-cyclopenta[1,3,2]dioxathiole 2,2-dioxide

Guidance literature:: Multi-step reaction with 2 steps

1: SOCl₂; Et₃N / CH₂Cl₂ / 0 °C

2: RuCl₃*H₂O; NaIO₄; H₂O / CCl₄; acetonitrile

With ruthenium trichloride; sodium periodate; thionyl chloride; water; triethylamine; In tetrachloromethane; dichloromethane; acetonitrile; 1: Substitution / 2: Oxidation;
DOI:10.1039/a903160j

Reference yield:

: 3396-11-0
cesium acetate

: 247589-92-0
(3aS,4S,6S,6aR)-4-Benzyloxymethyl-6-(4-methoxy-benzyloxy)-4-methyl-tetrahydro-cyclopenta[1,3,2]dioxathiole 2,2-dioxide

: Acetic acid (2S,3S,5S)-3-benzyloxymethyl-2-hydroxy-5-(4-methoxy-benzyloxy)-3-methyl-cyclopentyl ester

Guidance literature:: cesium acetate; (3aS,4S,6S,6aR)-4-Benzyloxymethyl-6-(4-methoxy-benzyloxy)-4-methyl-tetrahydro-cyclopenta[1,3,2]dioxathiole 2,2-dioxide; In N,N-dimethyl-formamide; at 40 ℃;

With sulfuric acid; In tetrahydrofuran;
DOI:10.1039/a903160j