Technology Process of C28H41NO6SSi
There total 6 articles about C28H41NO6SSi which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
methanesulfonamide;
In
water; tert-butyl alcohol;
at 20 ℃;
for 240h;
optical yield given as %ee;
DOI:10.1002/anie.201106205
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: dmap; triethylamine / dichloromethane / 10 h / 0 - 20 °C
2.1: tetrabutylammomium bromide; sodium hydroxide / dichloromethane; water / 0.17 h / 20 °C
2.2: 0.67 h / 20 °C
3.1: tetrabutylammomium bromide; palladium diacetate; potassium carbonate; tris-(o-tolyl)phosphine / N,N-dimethyl-formamide / 2 h / 100 °C / Inert atmosphere
4.1: methanesulfonamide / water; tert-butyl alcohol / 240 h / 20 °C
With
dmap; methanesulfonamide; tetrabutylammomium bromide; palladium diacetate; potassium carbonate; triethylamine; tris-(o-tolyl)phosphine; sodium hydroxide;
In
dichloromethane; water; N,N-dimethyl-formamide; tert-butyl alcohol;
3.1: Heck reaction / 4.1: Sharpless dihydroxylation;
DOI:10.1002/anie.201106205
- Guidance literature:
-
Multi-step reaction with 2 steps
1: tetrabutylammomium bromide; palladium diacetate; potassium carbonate; tris-(o-tolyl)phosphine / N,N-dimethyl-formamide / 2 h / 100 °C / Inert atmosphere
2: methanesulfonamide / water; tert-butyl alcohol / 240 h / 20 °C
With
methanesulfonamide; tetrabutylammomium bromide; palladium diacetate; potassium carbonate; tris-(o-tolyl)phosphine;
In
water; N,N-dimethyl-formamide; tert-butyl alcohol;
1: Heck reaction / 2: Sharpless dihydroxylation;
DOI:10.1002/anie.201106205
