5,15-Diphenyl-21H,23H-porphine

Base Information

• Chemical Name: 5,15-Diphenyl-21H,23H-porphine
• CAS No.: 22112-89-6
• Molecular Formula: C32H22 N4
• Molecular Weight: 462.553
• Hs Code.: 2933990090
• DSSTox Substance ID: DTXSID60447492
• Nikkaji Number: J1.011.508F,J1.531.154A
• Pharos Ligand ID: P18SWTHVHRYB
• ChEMBL ID: CHEMBL207155
• Mol file: 22112-89-6.mol

Synonyms:5,15-diphenylporphyrin

Chemical Property of 5,15-Diphenyl-21H,23H-porphine

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Melting Point: >200℃
• Refractive Index: 1.705
• Boiling Point: 912.26°C at 760 mmHg
• Flash Point: 401.28°C
• PSA: 56.30000
• Density: 1.285g/cm³
• LogP: 4.02920
• Storage Temp.: +2C to +8C
• Solubility.: ≤2mg/ml in dimethyl formamide
• XLogP3: 7.2
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 462.18444672
• Heavy Atom Count: 36
• Complexity: 657

Purity/Quality:

97% ^*data from raw suppliers

5,15-Diphenylporphyrin ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C2=C3C=CC(=CC4=CC=C(N4)C(=C5C=CC(=N5)C=C6C=CC2=N6)C7=CC=CC=C7)N3
• Uses: 5,15-Diphenylporphyrin (cas# 22112-89-6) is a useful research chemical.

Technology Process of 5,15-Diphenyl-21H,23H-porphine

There total 21 articles about 5,15-Diphenyl-21H,23H-porphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

10-bromo-5,15-diphenylporphyrin → 5,15-diphenylporphyrin (22112-89-6)

Guidance literature:

With (tri-iso-propylsilyl)methylmagnesium chloride; palladium diacetate; CyJohnPhos; In tetrahydrofuran; at 60 ℃; for 12h; Inert atmosphere;

DOI:10.1021/jo302122f

Reference yield: 87.0%

(tri-iso-propylsilyl)methylmagnesium chloride + 10-bromo-5,15-diphenylporphyrin → 5,15-diphenyl-10-(triisopropylsilyl)methylporphyrin + 5,15-diphenylporphyrin (22112-89-6)

Guidance literature:

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; Diphenylphosphine oxide; In tetrahydrofuran; at 60 ℃; for 6h; Inert atmosphere;

DOI:10.1021/jo302122f

Reference yield: 80.0%

(5,15-diphenylporphyrinato)zinc(II) (156821-61-3) + thiophenol (108-98-5) → C38H26N4S + 5,15-diphenylporphyrin (22112-89-6)

Guidance literature:

With sodium tetrachloroaurate(III) dihydrate; [bis(acetoxy)iodo]benzene; In dichloromethane; at 25 ℃;

DOI:10.1021/jo801855d

upstream raw materials:

(Z)-2-(phenyl(2H-pyrrol-2-ylidene)methyl)-1H-pyrrole

trimethyl orthoformate

2-pyrrole aldehyde

di(pyrrol-2-yl)methane

Downstream raw materials:

5,15-dibromo-10,20-diphenylporphyrin