[(2,6-(i-Pr)2C₆H₃NC(t-Bu)CHC(t-Bu)N-2,6-(i-Pr)2C₆H₃)ScCl₂]

Base Information

Chemical Name:[(2,6-(i-Pr)2C₆H₃NC(t-Bu)CHC(t-Bu)N-2,6-(i-Pr)2C₆H₃)ScCl₂]
CAS No.:241165-09-3
Molecular Formula:C₃₅H₅₃Cl₂N₂Sc
Molecular Weight:617.681
Hs Code.:

[(2,6-(i-Pr)2C<sub>6</sub>H<sub>3</sub>NC(t-Bu)CHC(t-Bu)N-2,6-(i-Pr)2C<sub>6</sub>H<sub>3</sub>)ScCl<sub>2</sub>]

Synonyms:[(2,6-(i-Pr)2C₆H₃NC(t-Bu)CHC(t-Bu)N-2,6-(i-Pr)2C₆H₃)ScCl₂]

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Chemical Property of [(2,6-(i-Pr)2C₆H₃NC(t-Bu)CHC(t-Bu)N-2,6-(i-Pr)2C₆H₃)ScCl₂]

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Technology Process of [(2,6-(i-Pr)2C₆H₃NC(t-Bu)CHC(t-Bu)N-2,6-(i-Pr)2C₆H₃)ScCl₂]

There total 1 articles about [(2,6-(i-Pr)2C₆H₃NC(t-Bu)CHC(t-Bu)N-2,6-(i-Pr)2C₆H₃)ScCl₂] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: scandium trichloride*3tetrahydrofuran

: 350609-70-0
Li(C₃H(C(CH₃)3)2(NC₆H₃(CH(CH₃)2)2)2)

: 241165-09-3
[(2,6-(i-Pr)2C₆H₃NC(t-Bu)CHC(t-Bu)N-2,6-(i-Pr)2C₆H₃)ScCl₂]

Guidance literature:: In toluene; byproducts: LiCl; under Ar; toluene condensed into flask contg. Li salt and ScCl3; mixt. sealed; heated to 110°C for 3 ds; hot filtered; toluene removed (vac.); trituration of residue with hexane; filtration; elem. anal.;
DOI:10.1021/om010131o

Reference yield: 89.0%

: 241165-09-3
[(2,6-(i-Pr)2C₆H₃NC(t-Bu)CHC(t-Bu)N-2,6-(i-Pr)2C₆H₃)ScCl₂]

: 241165-13-9
((2,6-iPr₂-C₆H₃)NC(tBu)CHC(tBu)N(2,6-iPr₂-C₆H₃))Sc(methyl)2

: 350609-81-3
Sc(C₃HN₂(C₄H₉)2(C₆H₃(C₃H₇)2)2)(CH₃)Cl

Guidance literature:: In toluene; under Ar; toluene was condensed into flask contg. Sc complexes at -78°C; graduelly warmed to room temp.; stirred for 90 min; solvent removed (vac.); hexane added; mixt. filtered; solvent removed (vac.); recrystd. (hexane) at -35°C; elem. anal.;
DOI:10.1021/om010131o

Reference yield: 82.0%

: 241165-09-3
[(2,6-(i-Pr)2C₆H₃NC(t-Bu)CHC(t-Bu)N-2,6-(i-Pr)2C₆H₃)ScCl₂]

: 24544-04-5
2,6-diisopropylbenzenamine

: 917-54-4
methyllithium

: 691888-02-5
[(2,6-diisopropylphenyl)NC(t-Bu)CHC(t-Bu)N(2,6-diisopropylphenyl)]Sc(Me)(NH-2,6-diisopropylphenyl)

Guidance literature:: [(2,6-(i-Pr)2C₆H₃NC(t-Bu)CHC(t-Bu)N-2,6-(i-Pr)2C₆H₃)ScCl₂]; methyllithium; In toluene; at -78 - 20 ℃;

2,6-diisopropylbenzenamine; In toluene; at 20 ℃; for 12h;
DOI:10.1021/om300913d