[(2,6-(i-Pr)2C₆H₃NC(t-Bu)CHC(t-Bu)N-2,6-(i-Pr)2C₆H₃)ScCl₂]

Base Information

• Chemical Name: [(2,6-(i-Pr)2C₆H₃NC(t-Bu)CHC(t-Bu)N-2,6-(i-Pr)2C₆H₃)ScCl₂]
• CAS No.: 241165-09-3
• Molecular Formula: C₃₅H₅₃Cl₂N₂Sc
• Molecular Weight: 617.681
• Mol file: 241165-09-3.mol

Synonyms:[(2,6-(i-Pr)2C₆H₃NC(t-Bu)CHC(t-Bu)N-2,6-(i-Pr)2C₆H₃)ScCl₂]

Chemical Property of [(2,6-(i-Pr)2C₆H₃NC(t-Bu)CHC(t-Bu)N-2,6-(i-Pr)2C₆H₃)ScCl₂]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(2,6-(i-Pr)2C₆H₃NC(t-Bu)CHC(t-Bu)N-2,6-(i-Pr)2C₆H₃)ScCl₂]

There total 1 articles about [(2,6-(i-Pr)2C₆H₃NC(t-Bu)CHC(t-Bu)N-2,6-(i-Pr)2C₆H₃)ScCl₂] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

scandium trichloride*3tetrahydrofuran + Li(C3H(C(CH3)3)2(NC6H3(CH(CH3)2)2)2) (350609-70-0) → [(2,6-(i-Pr)2C6H3NC(t-Bu)CHC(t-Bu)N-2,6-(i-Pr)2C6H3)ScCl2] (241165-09-3)

Guidance literature:

In toluene; byproducts: LiCl; under Ar; toluene condensed into flask contg. Li salt and ScCl3; mixt. sealed; heated to 110°C for 3 ds; hot filtered; toluene removed (vac.); trituration of residue with hexane; filtration; elem. anal.;

DOI:10.1021/om010131o

Reference yield: 89.0%

[(2,6-(i-Pr)2C6H3NC(t-Bu)CHC(t-Bu)N-2,6-(i-Pr)2C6H3)ScCl2] (241165-09-3) + ((2,6-iPr2-C6H3)NC(tBu)CHC(tBu)N(2,6-iPr2-C6H3))Sc(methyl)2 (241165-13-9) → Sc(C3HN2(C4H9)2(C6H3(C3H7)2)2)(CH3)Cl (350609-81-3)

Guidance literature:

In toluene; under Ar; toluene was condensed into flask contg. Sc complexes at -78°C; graduelly warmed to room temp.; stirred for 90 min; solvent removed (vac.); hexane added; mixt. filtered; solvent removed (vac.); recrystd. (hexane) at -35°C; elem. anal.;

DOI:10.1021/om010131o

Reference yield: 82.0%

[(2,6-(i-Pr)2C6H3NC(t-Bu)CHC(t-Bu)N-2,6-(i-Pr)2C6H3)ScCl2] (241165-09-3) + 2,6-diisopropylbenzenamine (24544-04-5) + methyllithium (917-54-4) → [(2,6-diisopropylphenyl)NC(t-Bu)CHC(t-Bu)N(2,6-diisopropylphenyl)]Sc(Me)(NH-2,6-diisopropylphenyl) (691888-02-5)

Guidance literature:

[(2,6-(i-Pr)2C₆H₃NC(t-Bu)CHC(t-Bu)N-2,6-(i-Pr)2C₆H₃)ScCl₂]; methyllithium; In toluene; at -78 - 20 ℃;

2,6-diisopropylbenzenamine; In toluene; at 20 ℃; for 12h;

DOI:10.1021/om300913d

upstream raw materials:

Li(C₃H(C(CH₃)3)2(NC₆H₃(CH(CH₃)2)2)2)

Downstream raw materials:

[Sc(CH₂C₆H₅)2(C₆H₃(CH(CH₃)2)2NCC(CH₃)3CHCC(CH₃)3NC₆H₃(CH(CH₃)2)2)]

Sc(C₃HN₂(C₄H₉)2(C₆H₃(C₃H₇)2)2)(CD₂CD₃)2

Sc(C₃HN₂(C₄H₉)2(C₆H₃(C₃H₇)2)2)(CH₃)Cl

((2,6-iPr₂-C₆H₃)NC(tBu)CHC(tBu)N(2,6-iPr₂-C₆H₃))Sc(methyl)2