(1R,2S,4S)-1-(hydroxymethyl)-2-(phenylselanyl)-4-(prop-1-en-2-yl)cyclohexanol

Base Information

Chemical Name:(1R,2S,4S)-1-(hydroxymethyl)-2-(phenylselanyl)-4-(prop-1-en-2-yl)cyclohexanol
CAS No.:94619-47-3
Molecular Formula:C₁₆H₂₂O₂Se
Molecular Weight:325.309
Hs Code.:

Synonyms:(1R,2S,4S)-1-(hydroxymethyl)-2-(phenylselanyl)-4-(prop-1-en-2-yl)cyclohexanol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1R,2S,4S)-1-(hydroxymethyl)-2-(phenylselanyl)-4-(prop-1-en-2-yl)cyclohexanol

Chemical Property:

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Technology Process of (1R,2S,4S)-1-(hydroxymethyl)-2-(phenylselanyl)-4-(prop-1-en-2-yl)cyclohexanol

There total 4 articles about (1R,2S,4S)-1-(hydroxymethyl)-2-(phenylselanyl)-4-(prop-1-en-2-yl)cyclohexanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 94597-66-7
(1R,2S,4S)-1-[(tert-butyldimethylsilyloxy)methyl]-2-(phenylselanyl)-4-(prop-1-en-2-yl)cyclohexanol

: 94619-47-3
(1R,2S,4S)-1-(hydroxymethyl)-2-(phenylselanyl)-4-(prop-1-en-2-yl)cyclohexanol

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 25 ℃; for 4h; Inert atmosphere;

Reference yield:

: 94597-63-4
(S)-tert-butyldimethyl[(4-(prop-1-en-2-yl)-7-oxabicyclo[4.1.0]heptan-1-yl)methoxy]silane

: 94619-47-3
(1R,2S,4S)-1-(hydroxymethyl)-2-(phenylselanyl)-4-(prop-1-en-2-yl)cyclohexanol

Guidance literature:: Multi-step reaction with 2 steps

1.1: sodium tetrahydroborate / ethanol / 1 h / 20 °C

1.2: 65 °C

2.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 4 h / 25 °C / Inert atmosphere

With sodium tetrahydroborate; tetrabutyl ammonium fluoride; In tetrahydrofuran; ethanol;

Reference yield:

: 536-59-4,18457-55-1
(-)-perillyl alcohol

: 94619-47-3
(1R,2S,4S)-1-(hydroxymethyl)-2-(phenylselanyl)-4-(prop-1-en-2-yl)cyclohexanol

Guidance literature:: Multi-step reaction with 4 steps

1.1: bis(acetylacetonate)oxovanadium; tert.-butylhydroperoxide / toluene; tert-butyl alcohol / 20 °C / Cooling with ice

2.1: 1H-imidazole / N,N-dimethyl-formamide / 0.17 h

2.2: 14 h

3.1: sodium tetrahydroborate / ethanol / 1 h / 20 °C

3.2: 65 °C

4.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 4 h / 25 °C / Inert atmosphere

With 1H-imidazole; tert.-butylhydroperoxide; sodium tetrahydroborate; bis(acetylacetonate)oxovanadium; tetrabutyl ammonium fluoride; In tetrahydrofuran; ethanol; N,N-dimethyl-formamide; toluene; tert-butyl alcohol;