(2R,3S)-(Z)-3-O-(tert-butyldiphenylsilyl)-5-undecene-1,2,3-triol

Base Information Edit

Chemical Name:(2R,3S)-(Z)-3-O-(tert-butyldiphenylsilyl)-5-undecene-1,2,3-triol
CAS No.:100333-62-8
Molecular Formula:C₂₇H₄₀O₃Si
Molecular Weight:440.698
Hs Code.:
Mol file:100333-62-8.mol

Synonyms:(2R,3S)-(Z)-3-O-(tert-butyldiphenylsilyl)-5-undecene-1,2,3-triol

Suppliers and Price of (2R,3S)-(Z)-3-O-(tert-butyldiphenylsilyl)-5-undecene-1,2,3-triol

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (2R,3S)-(Z)-3-O-(tert-butyldiphenylsilyl)-5-undecene-1,2,3-triol Edit

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (2R,3S)-(Z)-3-O-(tert-butyldiphenylsilyl)-5-undecene-1,2,3-triol

There total 11 articles about (2R,3S)-(Z)-3-O-(tert-butyldiphenylsilyl)-5-undecene-1,2,3-triol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 95646-05-2
3(S)-<(tert-butyldiphenylsilyl)oxy>-1,2-bis-O-(isopropylidene)-5(Z)-undecene-1,2(R)-diol

: 100333-62-8
(2R,3S)-(Z)-3-O-(tert-butyldiphenylsilyl)-5-undecene-1,2,3-triol

Guidance literature:: With trifluoroacetic acid; In tetrahydrofuran; Ambient temperature;
DOI:10.1021/jo00356a004

Reference yield:

: 93292-42-3
2-deoxy-3-O-(tert-butyldiphenylsilyl)-4,5-bis-O-(1-methylethylidene)-D-erythro-pentose

: 100333-62-8
(2R,3S)-(Z)-3-O-(tert-butyldiphenylsilyl)-5-undecene-1,2,3-triol

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) NaHMDS / 1.) THF, RT, 15 min, 2.) THF, from -78 deg C to RT, 18 h

2: 72 percent / aq. TFA / tetrahydrofuran / 10 h / 70 °C

With sodium hexamethyldisilazane; trifluoroacetic acid; In tetrahydrofuran;
DOI:10.1021/ja00128a008

Reference yield:

: 93292-41-2
2-deoxy-3-O-(tert-butyldiphenylsilyl)-4,5-O-isopropylidene-D-erythro-pentose diethyl dithioacetal

: 100333-62-8
(2R,3S)-(Z)-3-O-(tert-butyldiphenylsilyl)-5-undecene-1,2,3-triol

Guidance literature:: Multi-step reaction with 3 steps

1: 76 percent / N-chlorosuccinimide, aq. AgNO₃ / acetonitrile / 0.17 h / -20 °C

2: 1.) NaHMDS / 1.) THF, RT, 15 min, 2.) THF, from -78 deg C to RT, 18 h

3: 72 percent / aq. TFA / tetrahydrofuran / 10 h / 70 °C

With N-chloro-succinimide; sodium hexamethyldisilazane; silver nitrate; trifluoroacetic acid; In tetrahydrofuran; acetonitrile;
DOI:10.1021/ja00128a008