carbonic acid allyl ester (E)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-2-phenyl-vinyl ester

Base Information

Chemical Name:carbonic acid allyl ester (E)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-2-phenyl-vinyl ester
CAS No.:925462-06-2
Molecular Formula:C₁₉H₂₈O₄Si
Molecular Weight:348.514
Hs Code.:

Synonyms:carbonic acid allyl ester (E)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-2-phenyl-vinyl ester

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Chemical Property of carbonic acid allyl ester (E)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-2-phenyl-vinyl ester

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Technology Process of carbonic acid allyl ester (E)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-2-phenyl-vinyl ester

There total 2 articles about carbonic acid allyl ester (E)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-2-phenyl-vinyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

: 925462-44-8
carbonic acid allyl ester 1-methyl-2-oxo-2-phenyl-ethyl ester

: 18162-48-6
tert-butyldimethylsilyl chloride

: 925462-06-2
carbonic acid allyl ester (E)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-2-phenyl-vinyl ester

Guidance literature:: carbonic acid allyl ester 1-methyl-2-oxo-2-phenyl-ethyl ester; With sodium hexamethyldisilazane; In tetrahydrofuran; at -78 ℃; for 1h;

tert-butyldimethylsilyl chloride; In tetrahydrofuran; at -78 - 23 ℃;
DOI:10.1021/ja067342a

Reference yield:

: 2114-00-3
2-bromo-1-phenyl-1-propanone

: 925462-06-2
carbonic acid allyl ester (E)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-2-phenyl-vinyl ester

Guidance literature:: Multi-step reaction with 2 steps

1.1: 87 percent / dimethylformamide

2.1: sodium hexamethyldisilazane / tetrahydrofuran / 1 h / -78 °C

2.2: 66 percent / tetrahydrofuran / -78 - 23 °C

With sodium hexamethyldisilazane; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1021/ja067342a

Reference yield:

: 925462-06-2
carbonic acid allyl ester (E)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-2-phenyl-vinyl ester

: 925462-16-4
(R)-(+)-3-(tert-butyl-dimethyl-silanyloxy)-3-phenyl-hex-5-en-2-one

: 3-(tert-butyl-dimethyl-silanyloxy)-3-phenyl-hex-5-en-2-one

Guidance literature:: With chiral ligand; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; In 1,4-dioxane; at 23 ℃; for 12h; Title compound not separated from byproducts;
DOI:10.1021/ja067342a