(C₆H₅As)2Mo₆O₂₄^(4-)*4(C₄H₉)4N⁽¹⁺⁾=[(C₆H₅As)2Mo₆O₂₄](N(C₄H₉)4)4

Base Information

• Chemical Name: (C₆H₅As)2Mo₆O₂₄^(4-)*4(C₄H₉)4N⁽¹⁺⁾=[(C₆H₅As)2Mo₆O₂₄](N(C₄H₉)4)4
• CAS No.: 60187-14-6
• Molecular Formula: C₁₂H₁₀As₂Mo₆O₂₄*4C₁₆H₃₆N
• Molecular Weight: 2233.55
• Mol file: 60187-14-6.mol

Synonyms:(C₆H₅As)2Mo₆O₂₄^(4-)*4(C₄H₉)4N⁽¹⁺⁾=[(C₆H₅As)2Mo₆O₂₄](N(C₄H₉)4)4

Chemical Property of (C₆H₅As)2Mo₆O₂₄^(4-)*4(C₄H₉)4N⁽¹⁺⁾=[(C₆H₅As)2Mo₆O₂₄](N(C₄H₉)4)4

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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Useful:

Technology Process of (C₆H₅As)2Mo₆O₂₄^(4-)*4(C₄H₉)4N⁽¹⁺⁾=[(C₆H₅As)2Mo₆O₂₄](N(C₄H₉)4)4

There total 1 articles about (C₆H₅As)2Mo₆O₂₄^(4-)*4(C₄H₉)4N⁽¹⁺⁾=[(C₆H₅As)2Mo₆O₂₄](N(C₄H₉)4)4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 19.0%

sodium molybdate dihydrate (7631-95-0) + phenylarsonic acid (98-05-5) + tetrabutylammomium bromide (1643-19-2) → (C6H5As)2Mo6O24(4-)*4(C4H9)4N(1+)=[(C6H5As)2Mo6O24](N(C4H9)4)4 (60187-14-6)

Guidance literature:

With hydrogenchloride; In water; Conc. HCl was added to a stirred soln. of As- and Mo-compound, stirred for 15 min, the soln. of BuN4Br in water was added;; ppt. was collected, washed with water, ether, air-dried, stirred over P4O10 under vac. for 1 h; the soln. in MeCN was stirred on an 85°Coil bath for 24 h, cooled to -20°C; elem. anal.;;

DOI:10.1021/ja00310a033

Reference yield: 44.0%

tetrakis(tetrabutylammonium) octamolybdate + (C6H5As)2Mo6O24(4-)*4(C4H9)4N(1+)=[(C6H5As)2Mo6O24](N(C4H9)4)4 (60187-14-6) → (C6H5As)Mo7O25(4-)*4(C4H9)4N(1+)=[(C6H5As)Mo7O25](N(C4H9)4)4 (98509-06-9)

Guidance literature:

In acetonitrile; The soln. of reagents in MeCN was stirred in a 55°C oil bath for11 h, cooled to room temp.;; ether was added, ppt. was collected by filtration, washed with ether, dissolved in MeCN, toluene was added, the soln. was stored at -20°C for 24 h, crystals were filtered and dried in vac.; elem. anal.;;

DOI:10.1021/ja00310a033

Reference yield: 41.0%

(C6H5As)2Mo6O24(4-)*4(C4H9)4N(1+)=[(C6H5As)2Mo6O24](N(C4H9)4)4 (60187-14-6) + 17O-water (13968-48-4) → (C6H5As)2Mo6(17)O24(4-)*4(C4H9)4N(1+)=[(C6H5As)2Mo6(17)O24](N(C4H9)4)4

Guidance literature:

In acetonitrile; The soln. of complex and (17)OH2 in MeCN was stirred at ambient temp. for 1 h then at 65°C for 14 h, cooled to ambient temp.;; ether was added, filtered;;

DOI:10.1021/ja00310a033

upstream raw materials:

sodium molybdate dihydrate

phenylarsonic acid

tetrabutylammomium bromide

Downstream raw materials:

(C₆H₅As)Mo₇O₂₅^(4-)*4(C₄H₉)4N⁽¹⁺⁾=[(C₆H₅As)Mo₇O₂₅](N(C₄H₉)4)4