(+/-)3-(p-nitrophenyl)[3]ferrocenophane

Base Information

Chemical Name:(+/-)3-(p-nitrophenyl)[3]ferrocenophane
CAS No.:455886-72-3
Molecular Formula:C₁₉H₁₇FeNO₂
Molecular Weight:347.196
Hs Code.:

Synonyms:(+/-)3-(p-nitrophenyl)[3]ferrocenophane

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Chemical Property of (+/-)3-(p-nitrophenyl)[3]ferrocenophane

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Technology Process of (+/-)3-(p-nitrophenyl)[3]ferrocenophane

There total 1 articles about (+/-)3-(p-nitrophenyl)[3]ferrocenophane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 33.0%

: [3]ferrocenophane

: 100-01-6,104810-17-5
4-nitro-aniline

: 455886-72-3
(+/-)3-(p-nitrophenyl)[3]ferrocenophane

: 455886-74-5
(+/-)2-(p-nitrophenyl)[3]ferrocenophane

: 455886-76-7
(+/-)3,4'-bis(p-nitrophenyl)[3]ferrocenophane

: 455886-78-9
(+/-)3,4-bis(p-nitrophenyl)[3]ferrocenophane

Guidance literature:: With H₂SO₄; n-butyl nitrite; In diethyl ether; acetic acid; byproducts: n-butyl acetate; concd. H2SO4 added to soln. of aniline in glacial AcOH/ether; soln. of n-BuNO2 in ether added dropwise with stirring at 0°C over 15-20 min; suspn. reacted under stirring with Fe complex in ether for 2 h at 0-5°C; anhyd. Na2CO3 added over 1; h; mixt. stirred at 0-5°C for 2 h; warmed to 25°C overnight; filtered; evapd.; filter cake extd. (CH2Cl2); extract combined with residue; washed (H2O/ascorbic acid); dried (Na2SO4); evapd. (vac.); chromd. (Al2O3, C6H14/C7H8)/C6H6); recryst;
DOI:10.1016/S0022-328X(02)01113-0

Reference yield: 94.1%

: 455886-72-3
(+/-)3-(p-nitrophenyl)[3]ferrocenophane

: 1001400-85-6
3-(4-aminophenyl)[3]ferrocenophane

Guidance literature:: With hydrogenchloride; sodium carbonate; In water; isopropyl alcohol; reflux of mixt. of 3-(p-nitrophenyl)(3)ferrocenophane, SnCl2*2H2O and aq. HCl (concd.) for 2 h in mixt. i-propanol/H2O (1:1); addn. pH to 7 by addn. of Na2CO3; evapn. of isopropanol in rotary evaporator; extn. of suspn. with CH2Cl2;sepn. of aq. layer; extn. with CH2Cl2; drying of combined org. layers o ver an anhyd. Na2SO4; filtration, evapn. of CH2Cl2 to dryness; recrystn.from EtOH; elem. anal.;
DOI:10.1016/j.jorganchem.2007.09.010