3-(4-aminophenyl)[3]ferrocenophane

Base Information

• Chemical Name: 3-(4-aminophenyl)[3]ferrocenophane
• CAS No.: 1001400-85-6
• Molecular Formula: C₁₉H₁₉FeN
• Molecular Weight: 317.214
• Mol file: 1001400-85-6.mol

Synonyms:3-(4-aminophenyl)[3]ferrocenophane

Chemical Property of 3-(4-aminophenyl)[3]ferrocenophane

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

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Technology Process of 3-(4-aminophenyl)[3]ferrocenophane

There total 1 articles about 3-(4-aminophenyl)[3]ferrocenophane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.1%

(+/-)3-(p-nitrophenyl)[3]ferrocenophane (455886-72-3) → 3-(4-aminophenyl)[3]ferrocenophane (1001400-85-6)

Guidance literature:

With hydrogenchloride; sodium carbonate; In water; isopropyl alcohol; reflux of mixt. of 3-(p-nitrophenyl)(3)ferrocenophane, SnCl2*2H2O and aq. HCl (concd.) for 2 h in mixt. i-propanol/H2O (1:1); addn. pH to 7 by addn. of Na2CO3; evapn. of isopropanol in rotary evaporator; extn. of suspn. with CH2Cl2;sepn. of aq. layer; extn. with CH2Cl2; drying of combined org. layers o ver an anhyd. Na2SO4; filtration, evapn. of CH2Cl2 to dryness; recrystn.from EtOH; elem. anal.;

DOI:10.1016/j.jorganchem.2007.09.010

Reference yield: 87.3%

3-(4-aminophenyl)[3]ferrocenophane (1001400-85-6) + 2-hydroxy-4-n-dodecyloxybenzaldehyde (111772-62-4) → 3-[4-(2-hydroxy-4-dodecyloxybenzaldimino)phenyl][3]ferrocenophane (1001400-74-3)

Guidance literature:

In ethanol; dissolving of 3-(4-aminophenyl)(3)ferrocenophane (0.449 mmol) in min. amt. of hot EtOH; addn. to soln. of 2-hydroxy-4-dodecyloxybenzaldehyde (0.500 mmol); reflux for 0.5 - 1 h; cooling, pptn., filtration, recrystn. from EtOH or repptn. from CH2Cl2 soln. by addn. EtOH; elem. anal.;

DOI:10.1016/j.jorganchem.2007.09.010

Reference yield: 87.0%

3-(4-aminophenyl)[3]ferrocenophane (1001400-85-6) + 4-n-dodecyloxybenzaldehyde (24083-19-0) → 3-[4-(4-dodecyloxybenzaldimino)phenyl][3]ferrocenophane (1001400-73-2)

Guidance literature:

In ethanol; dissolving of 3-(4-aminophenyl)(3)ferrocenophane (1.618 mmol) in min. amt. of hot EtOH; addn. to soln. of 4-dodecyloxybenzaldehyde (1.706 mmol);reflux for 0.5 - 1 h; cooling, pptn., filtration, recrystn. from EtOH or repptn. from CH2Cl2 soln. by addn. EtOH; elem. anal.;

DOI:10.1016/j.jorganchem.2007.09.010

upstream raw materials:

(+/-)3-(p-nitrophenyl)[3]ferrocenophane

Downstream raw materials:

3-(4-[1-(4-dodecyloxybenzoyl)ethenyl-2-amino]phenyl)[3]ferrocenophane

3-[4-(4-dodecyloxybenzaldimino)phenyl][3]ferrocenophane

3-[4-(2-hydroxy-4-dodecyloxybenzaldimino)phenyl][3]ferrocenophane

3-(4-[4-(4-dodecyloxybenzoyloxy)benzaldimino]phenyl)[3]ferrocenophane