Cl₂BePt(P(C₆H₁₁)3)2

Base Information

• Chemical Name: Cl₂BePt(P(C₆H₁₁)3)2
• CAS No.: 1174209-46-1
• Molecular Formula: C₃₆H₆₆BeCl₂P₂Pt
• Molecular Weight: 835.866
• Mol file: 1174209-46-1.mol

Synonyms:Cl₂BePt(P(C₆H₁₁)3)2

Chemical Property of Cl₂BePt(P(C₆H₁₁)3)2

Chemical Property:

Purity/Quality:

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Technology Process of Cl₂BePt(P(C₆H₁₁)3)2

There total 1 articles about Cl₂BePt(P(C₆H₁₁)3)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

beryllium(II) chloride (7787-47-5) + bis(tricyclohexylphosphine)platinum(0) (55664-33-0) → Cl2BePt(P(C6H11)3)2 (1174209-46-1)

Guidance literature:

In benzene-d6; Ar, Schlenk and glovebox technique; BeCl2 added to soln. of Pt-complex, heated for 18 h at 80 °C; soln. layered with hexane, evapd. slowly in glovebox; elem. anal.;

DOI:10.1002/anie.200900521

Reference yield: 71.0%

Cl2BePt(P(C6H11)3)2 (1174209-46-1) + methyllithium (917-54-4) → CH3ClBePt(P(C6H11)3)2

Guidance literature:

In benzene-d6; Sonication; Ar, Schlenk and glovebox technique; Pt-Be complex treated with 2.4 equivalents of CH3Li in NMR tube, placed in ultrasonic bath for 1 min, heatedat 80 °C for 18 h; soln. filtered, filtrate layered with hexane, evapd. slo0wly in gloveboxat room temp.; elem. anal.;

DOI:10.1002/anie.200900521

Reference yield:

picoline (108-89-4) + Cl2BePt(P(C6H11)3)2 (1174209-46-1) → bis(tricyclohexylphosphine)platinum(0) (55664-33-0) + berillium chloride 4-methylpyridine adduct

Guidance literature:

DOI:10.1002/anie.200900521

upstream raw materials:

beryllium(II) chloride

bis(tricyclohexylphosphine)platinum⁽⁰⁾

Downstream raw materials:

bis(tricyclohexylphosphine)platinum⁽⁰⁾