2{(C₆H₅)3P}2N⁽¹⁺⁾*{Fe₄(CO)12C}^(2-)=C₈₅H₆₀N₂O₁₂Fe₄P₄

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Chemical Name:2{(C₆H₅)3P}2N⁽¹⁺⁾*{Fe₄(CO)12C}^(2-)=C₈₅H₆₀N₂O₁₂Fe₄P₄
CAS No.:74792-05-5
Molecular Formula:C₁₃Fe₄O₁₂*2C₃₆H₃₀NP₂
Molecular Weight:1648.7
Hs Code.:

2{(C<sub>6</sub>H<sub>5</sub>)3P}2N<sup>(1+)</sup>*{Fe<sub>4</sub>(CO)12C}<sup>(2-)</sup>=C<sub>85</sub>H<sub>60</sub>N<sub>2</sub>O<sub>12</sub>Fe<sub>4</sub>P<sub>4</sub>

Synonyms:2{(C₆H₅)3P}2N⁽¹⁺⁾*{Fe₄(CO)12C}^(2-)=C₈₅H₆₀N₂O₁₂Fe₄P₄

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Chemical Property of 2{(C₆H₅)3P}2N⁽¹⁺⁾*{Fe₄(CO)12C}^(2-)=C₈₅H₆₀N₂O₁₂Fe₄P₄

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Technology Process of 2{(C₆H₅)3P}2N⁽¹⁺⁾*{Fe₄(CO)12C}^(2-)=C₈₅H₆₀N₂O₁₂Fe₄P₄

There total 1 articles about 2{(C₆H₅)3P}2N⁽¹⁺⁾*{Fe₄(CO)12C}^(2-)=C₈₅H₆₀N₂O₁₂Fe₄P₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: CH^(3-)*HFe₄⁽³⁺⁾*12CO = HFe₄(CO)12(CH)

: 21050-13-5
bis(triphenylphosphine)iminium chloride

: 74792-05-5
2{(C₆H₅)3P}2N⁽¹⁺⁾*{Fe₄(CO)12C}^(2-)=C₈₅H₆₀N₂O₁₂Fe₄P₄

Guidance literature:: With KOH; In methanol; MeOH soln. of KOH was added to Fe complex (inert atm.), then PPNCl was added; washing with MeOH;
DOI:10.1021/ja00385a010

Reference yield: 75.0%

: [Mo(η-cyclopentadienyl)(CO)3(HgCl)]

: 74792-05-5
[PPN]2[Fe₄C(CO)12]

: [PPN][Fe4C(CO)12(μ-HgMo(CO)3Cp)]

Guidance literature:: With TlBF₄; In dichloromethane; byproducts: TlCl, (PPN)BF4; addn. of 1 equiv. of TlBF4 and 1 equiv. of Hg-compound to suspension of Fe-cluster at -5°C, stirring for 45 min; pptn. of by-products on addn. of cold ether, filtration, evapn., addn. of iPrOH, concn., crystn. on standing at -30°C overnight; elem. anal.;
DOI:10.1021/om9704657

Reference yield: 72.0%

: 421-20-5
Methyl fluorosulfonate

: 74792-05-5
2{(C₆H₅)3P}2N⁽¹⁺⁾*{Fe₄(CO)12C}^(2-)=C₈₅H₆₀N₂O₁₂Fe₄P₄

: {((C₆H₅)3P)2N}⁽¹⁺⁾*{Fe₄(CO)12CCH₃}^(1-)={((C₆H₅)3P)2N}{Fe₄(CO)12CCH₃}

Guidance literature:: In dichloromethane; MeSO3F was added to soln. of complex (inert atm., vac. techniques), react. for 1 h; evapn., dissoln. in ether, filtration, pptn. with hexane, filtration after crystn., drying in vac.; elem. anal.;
DOI:10.1021/ja00385a010