{Pd2Cl2(μ-(benzylthiomethyl)diphenylphosphine)2}*CH2Cl2

Base Information

• Chemical Name: {Pd2Cl2(μ-(benzylthiomethyl)diphenylphosphine)2}*CH2Cl2
• CAS No.: 130698-02-1
• Molecular Formula: CH₂Cl₂*C₄₀H₃₈Cl₂P₂Pd₂S₂
• Molecular Weight: 1013.5
• Mol file: 130698-02-1.mol

Synonyms:{Pd2Cl2(μ-(benzylthiomethyl)diphenylphosphine)2}*CH2Cl2

Chemical Property of {Pd2Cl2(μ-(benzylthiomethyl)diphenylphosphine)2}*CH2Cl2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of {Pd2Cl2(μ-(benzylthiomethyl)diphenylphosphine)2}*CH2Cl2

There total 2 articles about {Pd2Cl2(μ-(benzylthiomethyl)diphenylphosphine)2}*CH2Cl2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

{PdCl2((benzylthiomethyl)diphenylphosphine)2}*2CH2Cl2 + bis(dibenzylideneacetone)-palladium(0) (32005-36-0) → {Pd2Cl2(μ-(benzylthiomethyl)diphenylphosphine)2}*CH2Cl2 (130698-02-1)

Guidance literature:

In dichloromethane; react. under dry N2; addn. of Pd(dba)2 to a soln. of btmp-Komplex in CH2Cl2, stirring of red soln. for 3 h at room temp.; filtation, dilution with CH3OH; elem. anal.;

DOI:10.1246/bcsj.63.1961

Reference yield: 72.0%

dichloro bis(acetonitrile) palladium(II) (21264-30-2,90243-59-7,14592-56-4) + (benzylthiomethyl)diphenylphosphine (130365-32-1) + bis(dibenzylideneacetone)-palladium(0) (32005-36-0) → {Pd2Cl2(μ-(benzylthiomethyl)diphenylphosphine)2}*CH2Cl2 (130698-02-1)

Guidance literature:

In dichloromethane; react. under dry N2; reflux of PdCl2(NCCH3)2, Pd(dba)2, btmp in CH2Cl2 for 1 h; dilution of red soln. with CH3OH;

DOI:10.1246/bcsj.63.1961

Reference yield: 81.0%

{Pd2Cl2(μ-(benzylthiomethyl)diphenylphosphine)2}*CH2Cl2 (130698-02-1) + propynoic acid methyl ester (922-67-8) → {Pd2Cl2(μ-methyl propiolate)(μ-(benzylthiomethyl)diphenylphosphine)2}

Guidance literature:

In diethyl ether; dichloromethane; react. under dry N2; addn. of a soln. of methyl propiolate in CH2Cl2 to a suspension of Pd-complex in Et2O, color change from orange to pale yellow within 5 min; slow dilution with hexane, column chromy. of yellow ppt. (silica-gel, eluent: CH2Cl2/Et2O=10/1), evapn. of yellow fraction to dryness, recrystn. from C6H5-Et2O; elem. anal.;

DOI:10.1246/bcsj.63.1961

upstream raw materials:

dichloro bis(acetonitrile) palladium(II)

(benzylthiomethyl)diphenylphosphine

bis(dibenzylideneacetone)-palladium⁽⁰⁾

Downstream raw materials:

{Pd2I2(μ-(benzylthiomethyl)diphenylphosphine)2}