2-(2-Allylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Base Information

Chemical Name:2-(2-Allylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
CAS No.:857934-92-0
Molecular Formula:C₁₅H₂₁BO₂
Molecular Weight:244.142
Hs Code.:
European Community (EC) Number:853-920-7
Nikkaji Number:J2.190.605K

Synonyms:857934-92-0;2-(2-Allylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;(2-allylphenyl)boronic acid pinacol ester;4,4,5,5-tetramethyl-2-(2-prop-2-enylphenyl)-1,3,2-dioxaborolane;4,4,5,5-tetramethyl-2-[2-(prop-2-en-1-yl)phenyl]-1,3,2-dioxaborolane;1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-[2-(2-propenyl)phenyl]-;EN300-12732073

Suppliers and Price of 2-(2-Allylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Crysdot
2-(2-Allylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 95+%
1g
$ 465.00

Alichem
(2-Allylphenyl)boronicacidpinacolester
5g
$ 1834.47

Alichem
(2-Allylphenyl)boronicacidpinacolester
1g
$ 599.46

Total 3 raw suppliers

Chemical Property of 2-(2-Allylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:244.1634601
Heavy Atom Count:18
Complexity:296

Purity/Quality:

97% ^*data from raw suppliers

2-(2-Allylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 95+% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:B1(OC(C(O1)(C)C)(C)C)C2=CC=CC=C2CC=C

Technology Process of 2-(2-Allylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

There total 8 articles about 2-(2-Allylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 583-55-1
1-Bromo-2-iodobenzene

: 106-95-6
allyl bromide

: 73183-34-3
bis(pinacol)diborane

: 857934-92-0
4,4,5,5-tetramethyl-2-[2-(2-propenyl)phenyl]-1,3,2-dioxaborolane

Guidance literature:: bis(pinacol)diborane; With dimethyl zinc(II); magnesium 2-methylpropan-2-olate; In 1,4-dioxane; hexane; at 0 - 20 ℃; for 0.5h; Schlenk technique; Glovebox; Inert atmosphere;

1-Bromo-2-iodobenzene; In 1,4-dioxane; hexane; at 20 - 120 ℃; for 24h; Schlenk technique; Glovebox; Inert atmosphere;

allyl bromide; In 1,4-dioxane; hexane; at 20 - 75 ℃; for 12h; Schlenk technique; Glovebox; Inert atmosphere;
DOI:10.1021/ja409748m

Reference yield: 81.0%

: 615-42-9
1,2-Diiodobenzene

: 106-95-6
allyl bromide

: 73183-34-3
bis(pinacol)diborane

: 857934-92-0
4,4,5,5-tetramethyl-2-[2-(2-propenyl)phenyl]-1,3,2-dioxaborolane

Guidance literature:: bis(pinacol)diborane; With dimethyl zinc(II); magnesium 2-methylpropan-2-olate; In 1,4-dioxane; hexane; at 0 - 20 ℃; for 0.5h; Schlenk technique; Glovebox; Inert atmosphere;

1,2-Diiodobenzene; In 1,4-dioxane; hexane; at 20 - 120 ℃; for 24h; Schlenk technique; Glovebox; Inert atmosphere;

allyl bromide; In 1,4-dioxane; hexane; at 20 - 75 ℃; for 12h; Schlenk technique; Glovebox; Inert atmosphere;
DOI:10.1021/ja409748m

Reference yield: 76.0%

: BO₂(C(CH₃)2)2(C₆H₄MgCl)

: 106-95-6
allyl bromide

: 857934-92-0
4,4,5,5-tetramethyl-2-[2-(2-propenyl)phenyl]-1,3,2-dioxaborolane

Guidance literature:: copper(I) cyanide di(lithium chloride); In not given; reaction of BO2(C(CH3)2)2(C6H4MgCl) and CH2CHCH2Br transmetalated with CuCN*2LiCl;
DOI:10.1002/anie.200462928