(((acetylthio)methyl)bis(4-(3,3,4,4,5,5,6,6,6-nonafluorohexyl)phenyl)phosphonio)trihydroborate

Base Information

Chemical Name:(((acetylthio)methyl)bis(4-(3,3,4,4,5,5,6,6,6-nonafluorohexyl)phenyl)phosphonio)trihydroborate
CAS No.:1255763-11-1
Molecular Formula:C₂₇H₂₄BF₁₈OPS
Molecular Weight:780.309
Hs Code.:

Synonyms:(((acetylthio)methyl)bis(4-(3,3,4,4,5,5,6,6,6-nonafluorohexyl)phenyl)phosphonio)trihydroborate

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Chemical Property of (((acetylthio)methyl)bis(4-(3,3,4,4,5,5,6,6,6-nonafluorohexyl)phenyl)phosphonio)trihydroborate

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Technology Process of (((acetylthio)methyl)bis(4-(3,3,4,4,5,5,6,6,6-nonafluorohexyl)phenyl)phosphonio)trihydroborate

There total 4 articles about (((acetylthio)methyl)bis(4-(3,3,4,4,5,5,6,6,6-nonafluorohexyl)phenyl)phosphonio)trihydroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

: 54820-26-7
S-(bromomethyl)ethanethioate

: 1255763-10-0
(bis(4-(3,3,4,4,5,5,6,6,6-nonafluorohexyl)phenyl)phosphonio)trihydroborate

: 1255763-11-1
(((acetylthio)methyl)bis(4-(3,3,4,4,5,5,6,6,6-nonafluorohexyl)phenyl)phosphonio)trihydroborate

Guidance literature:: With NaH; In N,N-dimethyl-formamide; react. of B complex with NaH in DMF at 0°C for 12 h, then react. with CH3COSCH2Br;
DOI:10.1039/c0ob00564a

Reference yield:

: 1255763-09-7
(E)-1-bromo-4-(3,3,4,4,5,5,6,6,6-nonafluorohex-1-en-1-yl)benzene

: 1255763-11-1
(((acetylthio)methyl)bis(4-(3,3,4,4,5,5,6,6,6-nonafluorohexyl)phenyl)phosphonio)trihydroborate

Guidance literature:: Multi-step reaction with 4 steps

1.1: 5% Rh/C; hydrogen / dichloromethane / 24 h / 30 °C / 3750.38 Torr

2.1: diethylphosphoramidous dichloride; tert.-butyl lithium / diethyl ether / -78 - 0 °C / Inert atmosphere

2.2: 4 h / 0 - 20 °C

3.1: dimethylsulfide borane complex; water / tetrahydrofuran; diethyl ether / 0 - 20 °C / Inert atmosphere

4.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 0 °C / Inert atmosphere

4.2: 0 - 20 °C

With diethylphosphoramidous dichloride; dimethylsulfide borane complex; 5% Rh/C; water; hydrogen; tert.-butyl lithium; sodium hydride; In tetrahydrofuran; diethyl ether; dichloromethane; N,N-dimethyl-formamide; mineral oil;
DOI:10.1039/c0ob00564a

Reference yield:

: 1-bromo-4-(3,3,4,4,5,5,6,6,6-nonafluorohexyl)benzene

: 1255763-11-1
(((acetylthio)methyl)bis(4-(3,3,4,4,5,5,6,6,6-nonafluorohexyl)phenyl)phosphonio)trihydroborate

Guidance literature:: Multi-step reaction with 3 steps

1.1: diethylphosphoramidous dichloride; tert.-butyl lithium / diethyl ether / -78 - 0 °C / Inert atmosphere

1.2: 4 h / 0 - 20 °C

2.1: dimethylsulfide borane complex; water / tetrahydrofuran; diethyl ether / 0 - 20 °C / Inert atmosphere

3.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 0 °C / Inert atmosphere

3.2: 0 - 20 °C

With diethylphosphoramidous dichloride; dimethylsulfide borane complex; water; tert.-butyl lithium; sodium hydride; In tetrahydrofuran; diethyl ether; N,N-dimethyl-formamide; mineral oil;
DOI:10.1039/c0ob00564a