Bicyclo[3.1.0]hexan-3-one, 2-acetyl-6,6-dimethyl-, (1R,5R)- (9CI)

Base Information

Chemical Name:Bicyclo[3.1.0]hexan-3-one, 2-acetyl-6,6-dimethyl-, (1R,5R)- (9CI)
CAS No.:197440-66-7
Molecular Formula:C₁₀H₁₄O₂
Molecular Weight:166.22
Hs Code.:
Mol file:197440-66-7.mol

Synonyms:Bicyclo[3.1.0]hexan-3-one,2-acetyl-6,6-dimethyl-, (1R,5R)-[partial]-

Suppliers and Price of Bicyclo[3.1.0]hexan-3-one, 2-acetyl-6,6-dimethyl-, (1R,5R)- (9CI)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Crysdot
(1R,5R)-2-Acetyl-6,6-dimethylbicyclo[3.1.0]hexan-3-one 97%
1g
$ 1209.00

Total 1 raw suppliers

Chemical Property of Bicyclo[3.1.0]hexan-3-one, 2-acetyl-6,6-dimethyl-, (1R,5R)- (9CI)

Chemical Property:

Purity/Quality:: (1R,5R)-2-Acetyl-6,6-dimethylbicyclo[3.1.0]hexan-3-one 97% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Bicyclo[3.1.0]hexan-3-one, 2-acetyl-6,6-dimethyl-, (1R,5R)- (9CI)

There total 5 articles about Bicyclo[3.1.0]hexan-3-one, 2-acetyl-6,6-dimethyl-, (1R,5R)- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 79-20-9
acetic acid methyl ester

: 13855-29-3
6,6-Dimethylbicyclo<3.1.0.>hexan-3-one

: 197440-66-7
(1R,2R,5R)-2-acetyl-6,6-dimethyl-bicyclo[3.1.0]hexan-3-one

Guidance literature:: acetic acid methyl ester; With sodium hydride; In 1,4-dioxane; at 20 ℃; for 0.0833333h;

6,6-Dimethylbicyclo<3.1.0.>hexan-3-one; In 1,4-dioxane; at 65 ℃;

Reference yield:

: (1S,SR)-6,6-dimethyl-bicyclo[3.1.0]hexan-3-one

: 197440-66-7
(1R,2R,5R)-2-acetyl-6,6-dimethyl-bicyclo[3.1.0]hexan-3-one

Guidance literature:: In 1,4-dioxane; acetic acid methyl ester; mineral oil;

Reference yield:

: 498-15-7,19079-29-9
(+)-Δ³-carene

: 197440-66-7
(1R,5R)-2-Acetyl-6,6-dimethyl-bicyclo[3.1.0]hexan-3-one

Guidance literature:: Multi-step reaction with 3 steps

1.1: ozone / methanol / -65 °C

1.2: 2 h / 20 - 35 °C

2.1: thionyl chloride / 0.5 h / 0 °C

3.1: sodium methylate / methanol / 1 h / Reflux

With thionyl chloride; sodium methylate; ozone; In methanol; 3.1: |Dieckmann Condensation;
DOI:10.1021/jm4014373