N-BSMOC-GLYCINE

Base Information

Chemical Name:N-BSMOC-GLYCINE
CAS No.:197245-13-9
Molecular Formula:C12H11 N O6 S
Molecular Weight:297.288
Hs Code.:

Synonyms:BSMOC-GLYCINE;N-BSMOC-GLYCINE;N-(Benzo[b]thiophenesulphone-2-methoxycarbonyl)aminoacetic acid~N-(Benzo[b]thiophenesulphone-2-methoxycarbonyl)glycine~Bsmoc-Gly-OH;N-(Benzo[b]thiophenesulfone-2-methoxycarbonyl)aminoaceticacid;N-(Benzo[b]thiophenesulfone-2-methoxycarbonyl)glycine

Suppliers and Price of N-BSMOC-GLYCINE

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
N-BSMOC-GLYCINE 95.00%
5MG
$ 502.08

Alfa Aesar
N-Bsmoc-glycine, 99%
5g
$ 218.00

Alfa Aesar
N-Bsmoc-glycine, 99%
1g
$ 61.70

Alfa Aesar
N-Bsmoc-glycine, 99%
250mg
$ 22.40

Total 7 raw suppliers

Chemical Property of N-BSMOC-GLYCINE

Chemical Property:

Vapor Pressure:3.4E-16mmHg at 25°C
Melting Point:161-163°C
Refractive Index:1.62
Boiling Point:619.3°Cat760mmHg
Flash Point:328.3°C
PSA：118.15000
Density:1.533g/cm³
LogP:2.09730

Purity/Quality:

98%Min ^*data from raw suppliers

N-BSMOC-GLYCINE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Safety Statements: 22-24/25

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of N-BSMOC-GLYCINE

There total 6 articles about N-BSMOC-GLYCINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 623-33-6
glycine ethyl ester hydrochloride

: 197245-39-9
benzothiophenesulfone-2-(methoxycarbonyl)glycyl fluoride

: 197245-13-9
Bsmoc-Gly-OH

: Bsmoc-Gly-Gly-OEt

Guidance literature:: With N-ethyl-N,N-diisopropylamine; In dichloromethane; for 0.166667h;
DOI:10.1021/jo982140l

Reference yield:

: 50779-55-0
benzothiophen-2-yllithium

: 197245-13-9
Bsmoc-Gly-OH

Guidance literature:: Multi-step reaction with 4 steps

1: 2.) NaBH₄ / 2.) MeOH

2: 75 percent / sodium perborate tetrahydrate / acetic acid / 45 - 50 °C

3: 36.1 g / tetrahydrofuran / -30 - 20 °C

4: 1.) Me₃SiCl, 2.) i-Pr₂NEt / 1.) CH₂Cl₂, reflux, 1 h, 2.) 0 deg C 20 min,; room temperature, 1-1.5 h

With sodium perborate; sodium tetrahydroborate; chloro-trimethyl-silane; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; acetic acid;
DOI:10.1021/jo982140l

Reference yield:

: 17890-56-1
benzothiophene-2-methanol

: 197245-13-9
Bsmoc-Gly-OH

Guidance literature:: Multi-step reaction with 3 steps

1: 75 percent / sodium perborate tetrahydrate / acetic acid / 45 - 50 °C

2: 36.1 g / tetrahydrofuran / -30 - 20 °C

3: 1.) Me₃SiCl, 2.) i-Pr₂NEt / 1.) CH₂Cl₂, reflux, 1 h, 2.) 0 deg C 20 min,; room temperature, 1-1.5 h

With sodium perborate; chloro-trimethyl-silane; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; acetic acid;
DOI:10.1021/jo982140l