N-carbobenzoxy-5,6-O-isopropylidene-5,6,10-triepi-actinobolin

Base Information

Chemical Name:N-carbobenzoxy-5,6-O-isopropylidene-5,6,10-triepi-actinobolin
CAS No.:109124-42-7
Molecular Formula:C₂₄H₃₀N₂O₈
Molecular Weight:474.511
Hs Code.:

Synonyms:N-carbobenzoxy-5,6-O-isopropylidene-5,6,10-triepi-actinobolin

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Chemical Property of N-carbobenzoxy-5,6-O-isopropylidene-5,6,10-triepi-actinobolin

Chemical Property:

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Technology Process of N-carbobenzoxy-5,6-O-isopropylidene-5,6,10-triepi-actinobolin

There total 14 articles about N-carbobenzoxy-5,6-O-isopropylidene-5,6,10-triepi-actinobolin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 109215-72-7
>-<1-<1-<<(1,1-(dimethylethyl)dimethyl)silyl>oxy>ethyl>-4-oxo-2-pentenyl>carbamic acid phenylmethyl ester

: 109124-42-7
N-carbobenzoxy-5,6-O-isopropylidene-5,6,10-triepi-actinobolin

Guidance literature:: Multi-step reaction with 13 steps

1: 96 percent / triethylamine / benzene / 1.) 0 deg C, 5 min, 2.) RT, 15 min, 3.) 55 deg C, 6 h

2: 64 percent / benzene / 24 h / 110 °C / sealed tube

3: 1.) 1.0M borane 2.) 30percent H₂O₂, 2N NaOH / 1.) THF, 0 deg C, 1.5 h, 2.) 0 deg C, 0,5 h

4: 52percent HF / tetrahydrofuran; H₂O / 24 h / Ambient temperature

5: imidazole / dimethylformamide / 48 h / 55 °C

6: 94 percent / N-methylmorpholine-N-oxide / osmium tetroxide / acetone; H₂O / 24 h / Ambient temperature

7: tetrahydrofuran / 5 h / Heating

8: 85 percent / tri-n-butyltin hydride / benzene / 7 h / Heating

9: boron trifluoride etherate / acetonitrile / 0.5 h / 0 °C

10: Amberlyst 15 acidic resin / tetrahydrofuran / 6 h / Ambient temperature

11: 81 percent / pyridinium chlorochromate, sodium acetate / CH₂Cl₂ / 1 h / Ambient temperature

12: H₂ / 10percent palladium on carbon / CH₂Cl₂ / 1.5 h

13: CH₂Cl₂ / 1 h / 0 °C

With 1H-imidazole; sodium hydroxide; Amberlyst 15 acidic resin; boron trifluoride diethyl etherate; hydrogen fluoride; borane; hydrogen; dihydrogen peroxide; tri-n-butyl-tin hydride; sodium acetate; 4-methylmorpholine N-oxide; triethylamine; pyridinium chlorochromate; palladium on activated charcoal; osmium(VIII) oxide; In tetrahydrofuran; dichloromethane; water; N,N-dimethyl-formamide; acetone; acetonitrile; benzene;
DOI:10.1021/ja00251a021

Reference yield:

: 109215-73-8
>-<4-<<(1,1-dimethylethyl)dimethylsilyl>oxy>-1-<1-<<(1,1-dimethylethyl)dimethylsilyl>oxy>ethyl>-2,4-pentadienyl>carbamic acid phenylmethyl ester

: 109124-42-7
N-carbobenzoxy-5,6-O-isopropylidene-5,6,10-triepi-actinobolin

Guidance literature:: Multi-step reaction with 12 steps

1: 64 percent / benzene / 24 h / 110 °C / sealed tube

2: 1.) 1.0M borane 2.) 30percent H₂O₂, 2N NaOH / 1.) THF, 0 deg C, 1.5 h, 2.) 0 deg C, 0,5 h

3: 52percent HF / tetrahydrofuran; H₂O / 24 h / Ambient temperature

4: imidazole / dimethylformamide / 48 h / 55 °C

5: 94 percent / N-methylmorpholine-N-oxide / osmium tetroxide / acetone; H₂O / 24 h / Ambient temperature

6: tetrahydrofuran / 5 h / Heating

7: 85 percent / tri-n-butyltin hydride / benzene / 7 h / Heating

8: boron trifluoride etherate / acetonitrile / 0.5 h / 0 °C

9: Amberlyst 15 acidic resin / tetrahydrofuran / 6 h / Ambient temperature

10: 81 percent / pyridinium chlorochromate, sodium acetate / CH₂Cl₂ / 1 h / Ambient temperature

11: H₂ / 10percent palladium on carbon / CH₂Cl₂ / 1.5 h

12: CH₂Cl₂ / 1 h / 0 °C

With 1H-imidazole; sodium hydroxide; Amberlyst 15 acidic resin; boron trifluoride diethyl etherate; hydrogen fluoride; borane; hydrogen; dihydrogen peroxide; tri-n-butyl-tin hydride; sodium acetate; 4-methylmorpholine N-oxide; pyridinium chlorochromate; palladium on activated charcoal; osmium(VIII) oxide; In tetrahydrofuran; dichloromethane; water; N,N-dimethyl-formamide; acetone; acetonitrile; benzene;
DOI:10.1021/ja00251a021

Reference yield:

: 104410-89-1
<3aS-(3aα,8α,9α,9aα,9bβ)>-(3a,4,8,9,9a,9b-hexahydro-5-hydroxy-2,2,8-trimethyl-6-oxo-6H-1,3-dioxolo<4,5-f><2>benzopyran-9-yl)carbamic acid phenylmethyl ester

: 109124-42-7
N-carbobenzoxy-5,6-O-isopropylidene-5,6,10-triepi-actinobolin

Guidance literature:: Multi-step reaction with 2 steps

1: H₂ / 10percent palladium on carbon / CH₂Cl₂ / 1.5 h

2: CH₂Cl₂ / 1 h / 0 °C

With hydrogen; palladium on activated charcoal; In dichloromethane;
DOI:10.1021/ja00251a021