trans-hydridophenoxobis(triethylphosphine)platinum(II)

Base Information

• Chemical Name: trans-hydridophenoxobis(triethylphosphine)platinum(II)
• CAS No.: 120828-89-9
• Molecular Formula: C₁₈H₃₆OP₂Pt
• Molecular Weight: 525.511
• Mol file: 120828-89-9.mol

Synonyms:trans-hydridophenoxobis(triethylphosphine)platinum(II)

Chemical Property of trans-hydridophenoxobis(triethylphosphine)platinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of trans-hydridophenoxobis(triethylphosphine)platinum(II)

There total 4 articles about trans-hydridophenoxobis(triethylphosphine)platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

trans-hydrido(nitrato)bis(triethylphosphine)platinum(II) (19582-28-6,19566-92-8) + sodium phenoxide (139-02-6) → trans-hydridophenoxobis(triethylphosphine)platinum(II) (120828-89-9)

Guidance literature:

In methanol; benzene; (N2); benzene soln. of Pt complex was stirred with MeOH soln. of NaOPh for 15 min, solvent was removed in vac., residue extd. with pentane; combined exts. were concd., on cooling at -10°C overnight product pptd.;

DOI:10.1021/ja00195a031

Reference yield: 40.0%

trans-hydrido(phenylamido)bis(triethylphosphine)platinum(II) (110827-51-5) → trans-hydridophenoxobis(triethylphosphine)platinum(II) (120828-89-9)

Guidance literature:

With C₆H₅OH; In benzene; byproducts: aniline; (N2); to soln. of Pt complex was added excess phenol and solvent removed in vac.; from residual oil excess of phenol was sublimed off in vac., residue was extd. with pentane, on cooling exts. at - 10°C for several d crystals were obtained;

DOI:10.1021/ja00195a031

Reference yield:

trans-chlorohydridobis(triethylphosphine)platinum(II) (16842-17-4,20436-52-6,89254-73-9) → trans-hydridophenoxobis(triethylphosphine)platinum(II) (120828-89-9)

Guidance literature:

Multi-step reaction with 2 steps

1: TlNO₃ / acetonitrile; water

2: benzene; methanol

With TlNO₃; In methanol; water; acetonitrile; benzene;

DOI:10.1021/ja00195a031

upstream raw materials:

trans-hydrido(nitrato)bis(triethylphosphine)platinum(II)

sodium phenoxide

trans-hydrido(phenylamido)bis(triethylphosphine)platinum(II)

trans-chlorohydridobis(triethylphosphine)platinum(II)

Downstream raw materials:

trans-dihydridobis(triethylphosphine)platinum(II)

trans-hydrido(phenyl carbonato)bis(triethylphosphine)platinum(II)

(acrylonitrile)bis(triethylphosphine)platinum⁽⁰⁾

3-phenoxypropionitrile