PtHCl(triethylphosphine)2

Base Information

• Chemical Name: PtHCl(triethylphosphine)2
• CAS No.: 16842-17-4
• Molecular Formula: C₁₂H₃₁ClP₂Pt
• Molecular Weight: 467.859
• Mol file: 16842-17-4.mol

Synonyms:

Chemical Property of PtHCl(triethylphosphine)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of PtHCl(triethylphosphine)2

There total 29 articles about PtHCl(triethylphosphine)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

cis-dichlorobis(triethylphosphine)platinum(II) (13965-02-1,14177-93-6,15692-07-6) + chlorobenzene (108-90-7) → trans-bis(triethylphosphino)phenylchloro platinum(II) + trans-chlorohydridobis(triethylphosphine)platinum(II) (16842-17-4,20436-52-6,89254-73-9) + trans-{PtH(CH2CN)(PEt3)2} (118831-46-2)

Guidance literature:

In chlorobenzene; acetonitrile; Electrolysis; preelectrolyzing solvents/TBAP, adding cis-(PtCl2(PEt3)2), electrolyzing at -2.1 V to near zero current (Ar); filtering, evapg., adding charcoal, extg. (benzene), filtering, concg., chromy. (alumina, benzene/hexane), slow evapg.;

DOI:10.1021/om00106a032

Reference yield: 70.2%

cis-{Pt(PEt3)2(n-butyl)Cl} (89308-86-1) → 1-butylene (106-98-9,9003-28-5) + (Z)-2-Butene (590-18-1) + trans-chlorohydridobis(triethylphosphine)platinum(II) (16842-17-4,20436-52-6,89254-73-9) + trans-2-Butene (624-64-6)

Guidance literature:

In acetone; at 298.16 K; NMR; Kinetics;

Reference yield: 68.0%

cis-dichlorobis(triethylphosphine)platinum(II) (13965-02-1,14177-93-6,15692-07-6) → trans-chlorohydridobis(triethylphosphine)platinum(II) (16842-17-4,20436-52-6,89254-73-9) + trans-{PtCN(Ph)(PEt3)2} (33914-65-7)

Guidance literature:

With benzonitrile; In benzonitrile; acetonitrile; benzene; Electrolysis; preelectrolyzing solvents/TBAP, adding cis-(PtCl2(PEt3)2), electrolyzing at -2.1 V to near zero current (Ar, 3h); NMR;

DOI:10.1021/om00106a032

upstream raw materials:

bis(triethylphosphine)(oxalato)platinum(II)

cis-dichlorobis(triethylphosphine)platinum(II)

tetrabutylammonium perchlorate

chlorobenzene

Downstream raw materials:

trans-chlorohydridobis(tricyclohexylphosphine)platinum(II)

(CO)4Mo(μ-PPh2)(μ-H)Pt(PEt3)2

(CO)4W(μ-PPh2)(μ-H)Pt(PEt3)2

(CO)4Cr(μ-PPh2)(μ-H)Pt(PEt3)2