(1β,9aβ)-(+/-)-1,2,3,5,7,8,9,9a-octahydro-6-(phenylmethoxy)-1,8,8-trimethyl-6H-cyclopentacyclooctane

Base Information

Chemical Name:(1β,9aβ)-(+/-)-1,2,3,5,7,8,9,9a-octahydro-6-(phenylmethoxy)-1,8,8-trimethyl-6H-cyclopentacyclooctane
CAS No.:104070-42-0
Molecular Formula:C₂₁H₃₀O
Molecular Weight:298.469
Hs Code.:

Synonyms:(1β,9aβ)-(+/-)-1,2,3,5,7,8,9,9a-octahydro-6-(phenylmethoxy)-1,8,8-trimethyl-6H-cyclopentacyclooctane

Suppliers and Price of (1β,9aβ)-(+/-)-1,2,3,5,7,8,9,9a-octahydro-6-(phenylmethoxy)-1,8,8-trimethyl-6H-cyclopentacyclooctane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (1β,9aβ)-(+/-)-1,2,3,5,7,8,9,9a-octahydro-6-(phenylmethoxy)-1,8,8-trimethyl-6H-cyclopentacyclooctane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (1β,9aβ)-(+/-)-1,2,3,5,7,8,9,9a-octahydro-6-(phenylmethoxy)-1,8,8-trimethyl-6H-cyclopentacyclooctane

There total 21 articles about (1β,9aβ)-(+/-)-1,2,3,5,7,8,9,9a-octahydro-6-(phenylmethoxy)-1,8,8-trimethyl-6H-cyclopentacyclooctane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 57964-61-1
3-methyl-2-oxo-cyclopentanecarboxylic acid methyl ester

: 104070-42-0
(1β,9aβ)-(+/-)-1,2,3,5,7,8,9,9a-octahydro-6-(phenylmethoxy)-1,8,8-trimethyl-6H-cyclopentacyclooctane

Guidance literature:: Multi-step reaction with 19 steps

1: NaBH₄ / methanol / 0 °C

2: H₂SO₄ / diethyl ether

3: KO-t-Bu / tetrahydrofuran

4: DIBAH / toluene / -78 °C

5: NaH / tetrahydrofuran / 0 °C

6: 1.) O₃; 2.) Me₂S / 1.) CH₂Cl₂, -78 deg C; 2.) reflux

7: NaOH / methanol / Heating

8: DIBAH / diethyl ether / -100 °C

9: Et₂Zn / toluene / 60 °C

10: PCC / CH₂Cl₂

11: tetrahydrofuran

12: 99 percent / BF₃*Et₂O / diethyl ether

13: tetrahydrofuran / 0.08 h / -30 °C

14: hexane / 4 h / 50 °C

15: diethyl ether / -78 °C

16: PCC / CH₂Cl₂

17: Me₂S / diethyl ether

18: DIBAH / diethyl ether / -78 °C

19: 1.) KH / 1.) THF; 2.) THF

With sodium hydroxide; sodium tetrahydroborate; dimethylsulfide; boron trifluoride diethyl etherate; potassium tert-butylate; diethylzinc; potassium hydride; sodium hydride; diisobutylaluminium hydride; ozone; pyridinium chlorochromate; sulfuric acid; In tetrahydrofuran; methanol; diethyl ether; hexane; dichloromethane; toluene;
DOI:10.1021/ja00325a032

Reference yield:

: 170422-96-5
2-Hydroxy-3-methyl-cyclopentanecarboxylic acid methyl ester

: 104070-42-0
(1β,9aβ)-(+/-)-1,2,3,5,7,8,9,9a-octahydro-6-(phenylmethoxy)-1,8,8-trimethyl-6H-cyclopentacyclooctane

Guidance literature:: Multi-step reaction with 18 steps

1: H₂SO₄ / diethyl ether

2: KO-t-Bu / tetrahydrofuran

3: DIBAH / toluene / -78 °C

4: NaH / tetrahydrofuran / 0 °C

5: 1.) O₃; 2.) Me₂S / 1.) CH₂Cl₂, -78 deg C; 2.) reflux

6: NaOH / methanol / Heating

7: DIBAH / diethyl ether / -100 °C

8: Et₂Zn / toluene / 60 °C

9: PCC / CH₂Cl₂

10: tetrahydrofuran

11: 99 percent / BF₃*Et₂O / diethyl ether

12: tetrahydrofuran / 0.08 h / -30 °C

13: hexane / 4 h / 50 °C

14: diethyl ether / -78 °C

15: PCC / CH₂Cl₂

16: Me₂S / diethyl ether

17: DIBAH / diethyl ether / -78 °C

18: 1.) KH / 1.) THF; 2.) THF

With sodium hydroxide; dimethylsulfide; boron trifluoride diethyl etherate; potassium tert-butylate; diethylzinc; potassium hydride; sodium hydride; diisobutylaluminium hydride; ozone; pyridinium chlorochromate; sulfuric acid; In tetrahydrofuran; methanol; diethyl ether; hexane; dichloromethane; toluene;
DOI:10.1021/ja00325a032

Reference yield:

: 113472-65-4
(1β,2β,5β)-(+/-)-5-ethenyl-2-methylbicyclo<3.2.0>heptan-2-one

: 104070-42-0
(1β,9aβ)-(+/-)-1,2,3,5,7,8,9,9a-octahydro-6-(phenylmethoxy)-1,8,8-trimethyl-6H-cyclopentacyclooctane

Guidance literature:: Multi-step reaction with 7 steps

1: tetrahydrofuran / 0.08 h / -30 °C

2: hexane / 4 h / 50 °C

3: diethyl ether / -78 °C

4: PCC / CH₂Cl₂

5: Me₂S / diethyl ether

6: DIBAH / diethyl ether / -78 °C

7: 1.) KH / 1.) THF; 2.) THF

With dimethylsulfide; potassium hydride; diisobutylaluminium hydride; pyridinium chlorochromate; In tetrahydrofuran; diethyl ether; hexane; dichloromethane;
DOI:10.1021/ja00325a032