Cp'2Zr(H)Ph

Base Information

• Chemical Name: Cp'2Zr(H)Ph
• CAS No.: 112532-20-4
• Molecular Formula: C₂₆H₃₆Zr
• Molecular Weight: 439.796
• Mol file: 112532-20-4.mol

Synonyms:Cp'2Zr(H)Ph

Chemical Property of Cp'2Zr(H)Ph

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

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Technology Process of Cp'2Zr(H)Ph

There total 7 articles about Cp'2Zr(H)Ph which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.6%

(η5-pentamethylcyclopentadienyl)2(zirconium)(H)(iosbutyl)2 (67108-86-5) → Cp'2Zr(H)Ph (112532-20-4) + Isobutane (75-28-5,40921-86-6)

Guidance literature:

With benzene; In benzene; Irradiation (UV/VIS); (C5Me5)2Zr(H)CH2CH(CH3) in benzene is degassed and photolyzed with a blacklight for 10 days (vac.).; Evapn., addn. of petroleum ether at -78°C, stirring for several hours, cold filtn. of yellow solid, washing (cold petroleum ether), recrystn. (-78°C, petroleum ether), elem. anal.;

Reference yield: 46.0%

(pentamethylcyclopentadienyl)(π-η(5):σ-η(1)-tetramethylfulvene)phenylzirconium (105501-02-8) → Cp'2Zr(H)Ph (112532-20-4)

Guidance literature:

With H₂; In pentane; stirring of a soln. of Cp'Zr(Ph)(η1:η5-CH2C5Me4) in pentane (1 atm of H2, 30 min); redn. of vol., cooling (-78°C), filtration; elem. anal.;

DOI:10.1021/ja00231a020

Reference yield:

(η5-pentamethylcyclopentadienyl)2(zirconium)(ethyl)(H) (112532-21-5) → Cp'2Zr(H)Ph (112532-20-4)

Guidance literature:

With benzene; In benzene; byproducts: ethane; Irradiation (UV/VIS); Degassed sample is photolyzed with a blacklight for 10 days (vac.).;

upstream raw materials:

(η5-pentamethylcyclopentadienyl)2(zirconium)(ethyl)(H)

(η5-cyclopentadienyl)2(zirconium)(n-propyl)(H)

(η5-pentamethylcyclopentadienyl)2(zirconium)(H)(iosbutyl)2

(pentamethylcyclopentadienyl)2ZrH₂

Downstream raw materials:

(pentamethylcyclopentadienyl)(π-η(5):σ-η(1)-tetramethylfulvene)phenylzirconium