benzyl 2,3,6-trideoxy-4-O-trichloroacetimidoyl-α-L-threo-hex-2-enopyranoside

Base Information

Chemical Name:benzyl 2,3,6-trideoxy-4-O-trichloroacetimidoyl-α-L-threo-hex-2-enopyranoside
CAS No.:174151-43-0
Molecular Formula:C₁₅H₁₆Cl₃NO₃
Molecular Weight:364.656
Hs Code.:

Synonyms:benzyl 2,3,6-trideoxy-4-O-trichloroacetimidoyl-α-L-threo-hex-2-enopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of benzyl 2,3,6-trideoxy-4-O-trichloroacetimidoyl-α-L-threo-hex-2-enopyranoside

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Technology Process of benzyl 2,3,6-trideoxy-4-O-trichloroacetimidoyl-α-L-threo-hex-2-enopyranoside

There total 1 articles about benzyl 2,3,6-trideoxy-4-O-trichloroacetimidoyl-α-L-threo-hex-2-enopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 76404-33-6
Benzyl-2,3,6-tridesoxy-α-L-threo-hex-2-enopyranosid

: 545-06-2
trichloroacetonitrile

: 174151-43-0
benzyl 2,3,6-trideoxy-4-O-trichloroacetimidoyl-α-L-threo-hex-2-enopyranoside

Guidance literature:: With sodium hydride; Yield given. Multistep reaction; 1.) CH₂Cl₂, RT, 5 min, 2.) CH₂Cl₂, 0 deg C;
DOI:10.1016/0008-6215(95)00291-X

Reference yield: 68.0%

: 174151-43-0
benzyl 2,3,6-trideoxy-4-O-trichloroacetimidoyl-α-L-threo-hex-2-enopyranoside

: 174151-44-1
benzyl 2,3,4,6-tetradeoxy-2-trichloroacetamido-α-L-threo-hex-3-enopyranoside

Guidance literature:: In various solvent(s); at 160 ℃; for 5h;
DOI:10.1016/0008-6215(95)00291-X

Reference yield:

: 174151-43-0
benzyl 2,3,6-trideoxy-4-O-trichloroacetimidoyl-α-L-threo-hex-2-enopyranoside

: Acetic acid (2R,3R,4R,5S,6S)-3-acetylamino-2-benzyloxy-6-methyl-5-(toluene-4-sulfonylamino)-tetrahydro-pyran-4-yl ester

Guidance literature:: Multi-step reaction with 5 steps

1: 68 percent / various solvent(s) / 5 h / 160 °C

2: 83 percent / NaOH / ethanol / 2 h / 80 °C

3: 100 percent / pyridine

4: 39 percent / OsO₄ / TEBA / H₂O; 2-methyl-propan-2-ol; CHCl₃ / 72 h / 60 - 70 °C

5: 90 percent / pyridine

With pyridine; sodium hydroxide; osmium(VIII) oxide; N-benzyl-N,N,N-triethylammonium chloride; In ethanol; chloroform; water; tert-butyl alcohol;
DOI:10.1016/0008-6215(95)00291-X