76404-33-6Relevant academic research and scientific papers
Synthesis of the Hexasaccharide Fragment of Landomycin A Using a Mild, Reagent-Controlled Approach
Yalamanchili, Subbarao,Lloyd, DIna,Bennett, Clay S.
, p. 3674 - 3677 (2019)
The synthesis of the hexasaccharide fragment of landomycin A is reported. Using p-toluenesulfonyl chloride mediated dehydrative glycosylation, we constructed the deoxy-sugar linkages in a stereoselective fashion without the need for temporary prosthetic g
Reagent Controlled Direct Dehydrative Glycosylation with 2-Deoxy Sugars: Construction of the Saquayamycin Z Pentasaccharide
Mizia, J. Colin,Bennett, Clay S.
, p. 5922 - 5927 (2019/08/27)
The first synthesis of the pentasaccharide fragment of the angucycline antibiotic saquayamycin Z is described. By using our sulfonyl chloride mediated reagent controlled dehydrative glycosylation, we are able to assemble the glycosidic linkages with high
SYNTHESIS OF ISOMERIC BENZYL 6-DEOXY-α-L-TALO- AND α-L-GULOPYRANOSIDES
Banaszek, Anna
, p. 285 - 292 (2007/10/02)
Synthesis of benzyl 2,3,4-tri-O-acetyl-6-deoxy-α-L-talopyranoside (6) and its α-L-gulo isomer 7 was performed by a five-step sequence starting from L-rhamnal 1.The L-talo isomer was proved to be identical with the component of O-antigenic polysaccharide o
A convergent synthesis of optically active aspyrone
Sugiyama,Murayama,Yamashita
, p. 7343 - 7344 (2007/10/02)
Aspyrone (1) was elaborated in an optically pure form by the key reaction involving a nucleophilic addition of δ-lactone enolate to 2-tosyloxyaldehyde and a subsequent in situ formation of epoxide.
