[BzPh₃P][Au(m-nitrophenyl)Cl]

Base Information

• Chemical Name: [BzPh₃P][Au(m-nitrophenyl)Cl]
• CAS No.: 87961-64-6
• Molecular Formula: C₆H₄AuClNO₂*C₂₅H₂₂P
• Molecular Weight: 707.946
• Mol file: 87961-64-6.mol

Synonyms:[BzPh₃P][Au(m-nitrophenyl)Cl]

Chemical Property of [BzPh₃P][Au(m-nitrophenyl)Cl]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [BzPh₃P][Au(m-nitrophenyl)Cl]

There total 1 articles about [BzPh₃P][Au(m-nitrophenyl)Cl] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

P(C6H5)3(CH2C6H5)(1+)*AuCl2(1-)=(P(C6H5)3CH2C6H5)AuCl2 + bis(m-nitrophenyl)mercury (26953-06-0) → [BzPh3P][Au(m-nitrophenyl)Cl] (87961-64-6)

Guidance literature:

In acetone; to cold (0°C) soln. of Au complex in acetone Hg compd. added, stirred under N2 for 30 h at 2-4°C; concd. in vac., filtered into cold Et2O, cooled at -20°C, solid filtered off, washed with cold ether; elem. anal.;

DOI:10.1016/0022-328X(83)80090-4

Reference yield: 60.0%

[BzPh3P][Au(m-nitrophenyl)Cl] (87961-64-6) → (3-nitrophenyl)(triphenyl-λ5-phosphanyl)gold (87961-72-6)

Guidance literature:

With PPh₃; In acetone; to soln. of educt in acetone added soln. of PPh3 in acetone; concd., Et2O added, filtered, concd., n-hexane added; elem. anal.;

DOI:10.1016/0022-328X(83)80090-4

Reference yield:

[BzPh3P][Au(m-nitrophenyl)Cl] (87961-64-6) → gold (7440-57-5,457905-15-6)

Guidance literature:

In not given; decompn. at room temp. in soln. or in the solid state;

DOI:10.1016/0022-328X(83)80090-4

upstream raw materials:

bis(m-nitrophenyl)mercury

Downstream raw materials:

(3-nitrophenyl)(triphenyl-λ5-phosphanyl)gold

gold