trans-Pd(NO₂)2(PMePh₂)2

Base Information

Chemical Name:trans-Pd(NO₂)2(PMePh₂)2
CAS No.:73440-16-1
Molecular Formula:C₂₆H₂₆N₂O₄P₂Pd
Molecular Weight:598.871
Hs Code.:

trans-Pd(NO<sub>2</sub>)2(PMePh<sub>2</sub>)2

Synonyms:trans-Pd(NO₂)2(PMePh₂)2

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Chemical Property of trans-Pd(NO₂)2(PMePh₂)2

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Technology Process of trans-Pd(NO₂)2(PMePh₂)2

There total 2 articles about trans-Pd(NO₂)2(PMePh₂)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 7783-99-5
silver(I) nitrite

: Pd⁽²⁺⁾*2Cl^(1-)*2P(CH₃)(C₆H₅)2=[PdCl₂(P(CH₃)(C₆H₅)2)2]

: 73440-16-1
[Pd(NO₂)2((C₆H₅)2P(CH₃))2]

Guidance literature:: In methanol; dichloromethane; under argon, 1:3 mixt. in CH2Cl2, methanol added, stirred for 24 h, evapd.; extd. (CH2Cl2), filtered, evapd., elem. anal.;
DOI:10.1016/S0277-5387(00)00407-1

Reference yield:

: potassium tetranitropalladate (II)

: 1486-28-8
diphenyl(methyl)phosphine

: 73440-16-1
trans-Pd(NO₂)2(PMePh₂)2

Guidance literature:: In water; acetone; soln. of 1 equiv of K2Pd(NO2)4 in water/acetone (30/5) treated with 2 equiv of ligand, stirred for 2 h; ppt. dissolved by addition of CH2Cl2 with stirring, yellow CH2Cl2 soln. sepd. from colourless aq. layer, dried, treated with hexane, crystd. on standing at 278°C; elem. anal.;

Reference yield:

: 73440-16-1
trans-Pd(NO₂)2(PMePh₂)2

: 73956-31-7
Pd₄(CO)5(P(CH₃)(C₆H₅)2)4

Guidance literature:: With CO; In dichloromethane; byproducts: N2O, CO2; excess CO (1 atm, 12 h); N2-satd. n-hexane added; elem. anal.;
DOI:10.1021/ja00526a056