(+/-)-methyl trans-dihydrojasmonate

Base Information

Chemical Name:(+/-)-methyl trans-dihydrojasmonate
CAS No.:2570-03-8
Molecular Formula:C₁₃H₂₂O₃
Molecular Weight:226.316
Hs Code.:
UNII:6F0IU8Y5DL,43CCU17TXN
DSSTox Substance ID:DTXSID40164857
Nikkaji Number:J1.438.708K
Wikidata:Q27264763

Synonyms:(+/-)-methyl trans-dihydrojasmonate

Suppliers and Price of (+/-)-methyl trans-dihydrojasmonate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of (+/-)-methyl trans-dihydrojasmonate

Chemical Property:

XLogP3:2.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:7
Exact Mass:226.15689456
Heavy Atom Count:16
Complexity:248

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CCCCCC1C(CCC1=O)CC(=O)OC
Isomeric SMILES:CCCCC[C@H]1[C@@H](CCC1=O)CC(=O)OC

Technology Process of (+/-)-methyl trans-dihydrojasmonate

There total 103 articles about (+/-)-methyl trans-dihydrojasmonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 24863-70-5
(3-oxo-2-pentyl-cyclopent-1-enyl)-acetic acid methyl ester

: 2570-03-8,2630-39-9,24851-98-7,39647-11-5,93452-03-0,133163-97-0,133163-98-1,128087-96-7
(+/-)-methyl dihydroepijasmonate

Guidance literature:: With hydrogen; palladium on activated charcoal; In methanol; for 24h; under 760 Torr; Ambient temperature;
DOI:10.1016/S0040-4039(00)88791-2

Reference yield: 93.0%

: 54562-27-5,84893-69-6,108102-95-0,109008-64-2,109361-58-2,109361-60-6,119009-18-6,119009-19-7,136845-16-4,143292-36-8,146143-16-0
((1R,2S,3R)-3-Hydroxy-2-pentyl-cyclopentyl)-acetic acid methyl ester

: 2570-03-8,2630-39-9,24851-98-7,39647-11-5,93452-03-0,133163-97-0,133163-98-1,128087-96-7
(+/-)-methyl dihydroepijasmonate

Guidance literature:: With dipyridinium dichromate; In dichloromethane; for 44h;

Reference yield:

: 25564-22-1
2-pentyl-2-cyclopenten-1-one

: 2570-03-8,2630-39-9,24851-98-7,39647-11-5,93452-03-0,133163-97-0,133163-98-1,128087-96-7
(+/-)-methyl dihydroepijasmonate

Guidance literature:: Multi-step reaction with 4 steps

1.1: LiCl; CuI / diethyl ether; tetrahydrofuran / 0.08 h / -80 °C

1.2: diethyl ether; tetrahydrofuran / 1 h / -80 - -30 °C

1.3: 70 percent / 2-(methyliminomethyl)phenol / diethyl ether; tetrahydrofuran / -80 - 20 °C

2.1: O₃ / CH₂Cl₂ / 0.25 h / -80 °C

2.2: 70 percent / Me₂S / CH₂Cl₂ / -80 - 20 °C

3.1: NaH₂PO₄*H₂O; 30percent H₂O₂; NaClO₂ / H₂O; acetonitrile / 24 h / 20 °C

4.1: diethyl ether; methanol / 0.5 h / 20 °C

With sodium chlorite; sodium dihydrogenphosphate; copper(l) iodide; ozone; lithium chloride; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; water; acetonitrile;
DOI:10.1002/1099-0690(200110)2001:20<3837::AID-EJOC3837>3.0.CO;2-3