tert-Butyl-{3-[1-iodo-meth-(Z)-ylidene]-2-methylene-cyclohexyloxy}-dimethyl-silane

Base Information

Chemical Name:tert-Butyl-{3-[1-iodo-meth-(Z)-ylidene]-2-methylene-cyclohexyloxy}-dimethyl-silane
CAS No.:193622-64-9
Molecular Formula:C₁₄H₂₅IOSi
Molecular Weight:364.342
Hs Code.:

Synonyms:tert-Butyl-{3-[1-iodo-meth-(Z)-ylidene]-2-methylene-cyclohexyloxy}-dimethyl-silane

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Chemical Property of tert-Butyl-{3-[1-iodo-meth-(Z)-ylidene]-2-methylene-cyclohexyloxy}-dimethyl-silane

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Technology Process of tert-Butyl-{3-[1-iodo-meth-(Z)-ylidene]-2-methylene-cyclohexyloxy}-dimethyl-silane

There total 7 articles about tert-Butyl-{3-[1-iodo-meth-(Z)-ylidene]-2-methylene-cyclohexyloxy}-dimethyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: (1S,2S)-1-(tert-Butyl-dimethyl-silanyloxy)-2-iodomethyl-3-[1-iodo-1-trimethylsilanyl-meth-(Z)-ylidene]-cyclohexane

: 193622-64-9
tert-Butyl-{3-[1-iodo-meth-(Z)-ylidene]-2-methylene-cyclohexyloxy}-dimethyl-silane

Guidance literature:: With 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane; for 120h; Ambient temperature;
DOI:10.1021/jo970605m

Reference yield: 84.0%

: 193622-63-8
1-(tert-Butyl-dimethyl-silanyloxy)-3-[1-iodo-1-trimethylsilanyl-meth-(Z)-ylidene]-2-methylene-cyclohexane

: 193622-64-9
tert-Butyl-{3-[1-iodo-meth-(Z)-ylidene]-2-methylene-cyclohexyloxy}-dimethyl-silane

Guidance literature:: With caesium carbonate; In N,N-dimethyl-formamide; for 12h; Ambient temperature;
DOI:10.1016/S0040-4039(00)60832-8

Reference yield:

: 143660-74-6
⁽³⁾-tert-butyldimethyl(oct-1-en-7-yn-3-yloxy)silane

: 193622-64-9
tert-Butyl-{3-[1-iodo-meth-(Z)-ylidene]-2-methylene-cyclohexyloxy}-dimethyl-silane

Guidance literature:: Multi-step reaction with 3 steps

1: 88 percent / MeLi*LiBr / diethyl ether / 7 h / Ambient temperature

2: 1.) n-BuLi, Cp₂ZrCl₂, 2.) NIS / 1) hexane, THF, -80 --> -55 deg C, 1 h, rt, 7 h; 2) hexane, THF, CH₂Cl₂, -50 deg C, 1 h, rt, 1 h

3: 97 percent / DBU / CH₂Cl₂ / 120 h / Ambient temperature

With N-iodo-succinimide; n-butyllithium; zirconocene dichloride; methyllithium lithium bromide; 1,8-diazabicyclo[5.4.0]undec-7-ene; In diethyl ether; dichloromethane;
DOI:10.1021/jo970605m