C₄₅H₆₅N₄O₆SiBr

Base Information

Chemical Name:C₄₅H₆₅N₄O₆SiBr
CAS No.:943858-43-3
Molecular Formula:C₄₅H₆₅BrN₄O₆Si
Molecular Weight:866.024
Hs Code.:

C<sub>45</sub>H<sub>65</sub>N<sub>4</sub>O<sub>6</sub>SiBr

Synonyms:C₄₅H₆₅N₄O₆SiBr

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Chemical Property of C₄₅H₆₅N₄O₆SiBr

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Technology Process of C₄₅H₆₅N₄O₆SiBr

There total 21 articles about C₄₅H₆₅N₄O₆SiBr which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 943858-23-9
C₄₅H₆₇N₄O₇SiBr

: 943858-43-3
C₄₅H₆₅N₄O₆SiBr

Guidance literature:: C₄₅H₆₇N₄O₇SiBr; With 2,4,6-trichlorobenzoyl chloride; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; at 20 ℃; for 2.5h;

With dmap; In benzene; for 8h; Further stages.;
DOI:10.1021/ol070855h

Reference yield:

: C₂₂H₂₉NO₅

: 943858-43-3
C₄₅H₆₅N₄O₆SiBr

Guidance literature:: Multi-step reaction with 13 steps

1.1: 83 percent / LiBH₄ / ethanol; diethyl ether; tetrahydrofuran / 0.33 h / 0 °C

2.1: 24 mg / triphenylphosphine; diisopropyl azodicarboxylate / tetrahydrofuran / 6 h / Heating

3.1: 81 percent / pyridine; AcOH; NaH₂PO₃*H₂O / Raney nickel / H₂O / 6 h / 50 °C

4.1: tetrahydrofuran / 0.5 h / 0 °C

5.1: triphenylphosphine; diisopropyl azodicarboxylate / diethyl ether / 10 h / 20 °C

6.1: 7.8 mg / potassium carbonate / ethanol / 5 h / 20 °C

7.1: 98 percent / Et₃N / CH₂Cl₂ / 3 h / 20 °C

8.1: 95 percent / aq. lithium hydroxide / tetrahydrofuran; methanol / 6 h / 20 °C

9.1: 80 percent / DCC; HOBt / 24 h / 0 - 20 °C

10.1: 96 percent / aq. lithium hydroxide / tetrahydrofuran; methanol / 2 h / 20 °C

11.1: 2,6-lutidine / CH₂Cl₂ / 1 h / 20 °C

12.1: 80 percent / aq. potassium carbonate / tetrahydrofuran; methanol / 0.5 h / 20 °C

13.1: DIPEA; 2,4,6-trichlorobenzoyl chloride / tetrahydrofuran / 2.5 h / 20 °C

13.2: 82 percent / DMAP / benzene / 8 h

With pyridine; 2,6-dimethylpyridine; lithium hydroxide; lithium borohydride; sodium dihydrogen phosphate; di-isopropyl azodicarboxylate; 2,4,6-trichlorobenzoyl chloride; potassium carbonate; benzotriazol-1-ol; acetic acid; triethylamine; N-ethyl-N,N-diisopropylamine; dicyclohexyl-carbodiimide; triphenylphosphine; nickel; In tetrahydrofuran; methanol; diethyl ether; ethanol; dichloromethane; water; 2.1: Mitsunobu reaction / 5.1: Mitsunobu reaction;
DOI:10.1021/ol070855h

Reference yield:

: 226703-78-2
C₁₇H₂₁NO₄

: 943858-43-3
C₄₅H₆₅N₄O₆SiBr

Guidance literature:: Multi-step reaction with 14 steps

1.1: 93 percent / propionic acid / 1 h / 140 °C

2.1: 83 percent / LiBH₄ / ethanol; diethyl ether; tetrahydrofuran / 0.33 h / 0 °C

3.1: 24 mg / triphenylphosphine; diisopropyl azodicarboxylate / tetrahydrofuran / 6 h / Heating

4.1: 81 percent / pyridine; AcOH; NaH₂PO₃*H₂O / Raney nickel / H₂O / 6 h / 50 °C

5.1: tetrahydrofuran / 0.5 h / 0 °C

6.1: triphenylphosphine; diisopropyl azodicarboxylate / diethyl ether / 10 h / 20 °C

7.1: 7.8 mg / potassium carbonate / ethanol / 5 h / 20 °C

8.1: 98 percent / Et₃N / CH₂Cl₂ / 3 h / 20 °C

9.1: 95 percent / aq. lithium hydroxide / tetrahydrofuran; methanol / 6 h / 20 °C

10.1: 80 percent / DCC; HOBt / 24 h / 0 - 20 °C

11.1: 96 percent / aq. lithium hydroxide / tetrahydrofuran; methanol / 2 h / 20 °C

12.1: 2,6-lutidine / CH₂Cl₂ / 1 h / 20 °C

13.1: 80 percent / aq. potassium carbonate / tetrahydrofuran; methanol / 0.5 h / 20 °C

14.1: DIPEA; 2,4,6-trichlorobenzoyl chloride / tetrahydrofuran / 2.5 h / 20 °C

14.2: 82 percent / DMAP / benzene / 8 h

With pyridine; 2,6-dimethylpyridine; lithium hydroxide; lithium borohydride; sodium dihydrogen phosphate; di-isopropyl azodicarboxylate; 2,4,6-trichlorobenzoyl chloride; potassium carbonate; benzotriazol-1-ol; acetic acid; propionic acid; triethylamine; N-ethyl-N,N-diisopropylamine; dicyclohexyl-carbodiimide; triphenylphosphine; nickel; In tetrahydrofuran; methanol; diethyl ether; ethanol; dichloromethane; water; 1.1: Claisen orthoester rearrangement / 3.1: Mitsunobu reaction / 6.1: Mitsunobu reaction;
DOI:10.1021/ol070855h