(3,5-(CF₃)2C₆H₃-N=CMe-CMe=N-3,5-(CF₃)2C₆H₃)Pt(p-Tol)(NCMe)BF₄

Base Information

• Chemical Name: (3,5-(CF₃)2C₆H₃-N=CMe-CMe=N-3,5-(CF₃)2C₆H₃)Pt(p-Tol)(NCMe)BF₄
• CAS No.: 355840-59-4
• Molecular Formula: BF₄*C₂₉H₂₂F₁₂N₃Pt
• Molecular Weight: 922.379
• Mol file: 355840-59-4.mol

Synonyms:(3,5-(CF₃)2C₆H₃-N=CMe-CMe=N-3,5-(CF₃)2C₆H₃)Pt(p-Tol)(NCMe)BF₄

Chemical Property of (3,5-(CF₃)2C₆H₃-N=CMe-CMe=N-3,5-(CF₃)2C₆H₃)Pt(p-Tol)(NCMe)BF₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (3,5-(CF₃)2C₆H₃-N=CMe-CMe=N-3,5-(CF₃)2C₆H₃)Pt(p-Tol)(NCMe)BF₄

There total 3 articles about (3,5-(CF₃)2C₆H₃-N=CMe-CMe=N-3,5-(CF₃)2C₆H₃)Pt(p-Tol)(NCMe)BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

tetrafluoroboric acid + (3,5-(CF3)2C6H3-N=CMe-CMe=N-3,5-(CF3)2C6H3)Pt(p-Tol)2 (355840-53-8) + acetonitrile (75-05-8,26809-02-9) → (3,5-(CF3)2C6H3-N=CMe-CMe=N-3,5-(CF3)2C6H3)Pt(p-Tol)(NCMe)BF4 (355840-59-4)

Guidance literature:

In diethyl ether; acetonitrile; soln. HBF4 in Et2O was added to soln. platinum complex in MeCN and stirred for 20 min; solvent was removed, residue was washed with Et2O and dissolved in acetone, Et2O was added; elem. anal.;

DOI:10.1021/ja010277e

Reference yield:

cis-[Pt(p-CH3C6H4)2(S(CH3)2)2] (64827-21-0,84414-96-0) + N,N’-bis-(3,5di(trifluoromethyl)phenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene (400608-66-4) → (3,5-(CF3)2C6H3-N=CMe-CMe=N-3,5-(CF3)2C6H3)Pt(p-Tol)(NCMe)BF4 (355840-59-4)

Guidance literature:

Multi-step reaction with 2 steps

1: toluene

2: acetonitrile; diethyl ether

In diethyl ether; toluene; acetonitrile;

DOI:10.1021/ja010277e

Reference yield:

(3,5-(CF3)2C6H3-N=CMe-CMe=N-3,5-(CF3)2C6H3)Pt(CH3)(H2O)BF4 (222736-32-5) + toluene (108-88-3,15644-74-3,16713-13-6) → (3,5-(CF3)2C6H3-N=CMe-CMe=N-3,5-(CF3)2C6H3)Pt(o-Tol)(NCMe)(1+) (355840-54-9) + (3,5-(CF3)2C6H3-N=CMe-CMe=N-3,5-(CF3)2C6H3)Pt(m-Tol)(NCMe)BF4 (355840-57-2) + (3,5-(CF3)2C6H3-N=CMe-CMe=N-3,5-(CF3)2C6H3)Pt(p-Tol)(NCMe)BF4 (355840-59-4)

Guidance literature:

In further solvent(s); react. with toluene in trifluoroethanol-d3;

DOI:10.1021/ja010277e

upstream raw materials:

(3,5-(CF₃)2C₆H₃-N=CMe-CMe=N-3,5-(CF₃)2C₆H₃)Pt(CH₃)(H₂O)BF₄

toluene

(3,5-(CF₃)2C₆H₃-N=CMe-CMe=N-3,5-(CF₃)2C₆H₃)Pt(p-Tol)2

acetonitrile