1,7-Dioxaspiro5.5undecan-3-ol, 5-methoxy-, (3.alpha.,5.alpha.,6.beta.)-

Base Information

Chemical Name:1,7-Dioxaspiro5.5undecan-3-ol, 5-methoxy-, (3.alpha.,5.alpha.,6.beta.)-
CAS No.:191659-86-6
Molecular Formula:C₁₀H₁₈O₄
Molecular Weight:202.251
Hs Code.:
Mol file:191659-86-6.mol

Synonyms:1,7-Dioxaspiro[5.5]undecan-3-ol,5-methoxy-, (3a,5a,6b)- (9CI)

Suppliers and Price of 1,7-Dioxaspiro5.5undecan-3-ol, 5-methoxy-, (3.alpha.,5.alpha.,6.beta.)-

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1,7-Dioxaspiro5.5undecan-3-ol, 5-methoxy-, (3.alpha.,5.alpha.,6.beta.)-

Chemical Property:

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Technology Process of 1,7-Dioxaspiro5.5undecan-3-ol, 5-methoxy-, (3.alpha.,5.alpha.,6.beta.)-

There total 8 articles about 1,7-Dioxaspiro5.5undecan-3-ol, 5-methoxy-, (3.alpha.,5.alpha.,6.beta.)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 13.0%

: 191659-80-0
[3S*,4S*,5S*,6S*]-3,4-epoxy-5-methoxy-1,7-dioxaspiro[5.5]undecane

: 191659-86-6
(3S,5R,6R)-5-Methoxy-1,7-dioxa-spiro[5.5]undecan-3-ol

: (4R,5R,6R)-5-Methoxy-1,7-dioxa-spiro[5.5]undecan-4-ol

Guidance literature:: With lithium aluminium tetrahydride; In tetrahydrofuran;
DOI:10.1021/jo971172q

Reference yield: 13.0%

: 191659-80-0
C₁₀H₁₆O₄

: 191659-86-6
(3S,5R,6R)-5-Methoxy-1,7-dioxa-spiro[5.5]undecan-3-ol

: (4R,5R,6R)-5-Methoxy-1,7-dioxa-spiro[5.5]undecan-4-ol

Guidance literature:: With lithium aluminium tetrahydride; In tetrahydrofuran; for 12h; Ambient temperature;
DOI:10.1016/S0040-4039(97)00671-0

Reference yield:

: 189508-45-0
[5S*,6S*]-1,7-dioxaspiro[5.5]undec-3-en-5-ol

: 191659-86-6
(3S,5R,6R)-5-Methoxy-1,7-dioxa-spiro[5.5]undecan-3-ol

Guidance literature:: Multi-step reaction with 3 steps

1: 92 percent / m-CPBA, NaOAc / CH₂Cl₂ / 1.) 0 deg C -> room temperature, 2.) room temperature, 72 h

2: 87 percent / NaH / tetrahydrofuran / 1.) 0 deg C -> room temperature, 2.) room temperature, 3 h

3: 63 percent / LiAlH₄ / tetrahydrofuran

With lithium aluminium tetrahydride; sodium acetate; sodium hydride; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo971172q