(5S,6S)-1,7-dioxaspiro[5.5]undec-3-en-5-ol

Base Information

Chemical Name:(5S,6S)-1,7-dioxaspiro[5.5]undec-3-en-5-ol
CAS No.:189508-45-0
Molecular Formula:C₉H₁₄O₃
Molecular Weight:170.208
Hs Code.:
Nikkaji Number:J846.923G
Mol file:189508-45-0.mol

Synonyms:(5S,6S)-1,7-dioxaspiro[5.5]undec-3-en-5-ol;189508-45-0;1,7-Dioxaspiro5.5undec-3-en-5-ol, trans-;TRANS-1,7-DIOXASPIRO[5.5]UNDEC-3-EN-5-OL

Suppliers and Price of (5S,6S)-1,7-dioxaspiro[5.5]undec-3-en-5-ol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of (5S,6S)-1,7-dioxaspiro[5.5]undec-3-en-5-ol

Chemical Property:

XLogP3:0.3
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:0
Exact Mass:170.094294304
Heavy Atom Count:12
Complexity:190

Purity/Quality:: 98% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1CCOC2(C1)C(C=CCO2)O
Isomeric SMILES:C1CCO[C@]2(C1)[C@H](C=CCO2)O

Technology Process of (5S,6S)-1,7-dioxaspiro[5.5]undec-3-en-5-ol

There total 4 articles about (5S,6S)-1,7-dioxaspiro[5.5]undec-3-en-5-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: (R)-1-((R)-2-Allyloxy-tetrahydro-pyran-2-yl)-prop-2-en-1-ol

: 189508-45-0
(5S,6S)-1,7-Dioxa-spiro[5.5]undec-3-en-5-ol

Guidance literature:: Grubbs catalyst first generation; In benzene; at 20 ℃; for 0.5h;
DOI:10.1016/j.tet.2006.06.113

Reference yield: 37.0%

: 191659-53-7,191659-50-4
[4S*,5S*,6S*]-4,5-epoxy-1,7-dioxaspiro[5.5]undecane

: 189508-45-0
[5S*,6S*]-1,7-dioxaspiro[5.5]undec-3-en-5-ol

: 191659-62-8
[5S*,6S*]-1,7-dioxaspiro[5.5]undec-2-en-5-ol

Guidance literature:: With lithium diethylamide; In hexane; 1.) -35 deg C -> room temperature, 2.) room temperature, 16 h;
DOI:10.1021/jo971172q

Reference yield:

: 191659-53-7,191659-50-4
C₉H₁₄O₃

: 189508-45-0
(5S,6S)-1,7-Dioxa-spiro[5.5]undec-3-en-5-ol

: 191659-62-8
(5S*,6S*)-1,7-Dioxaspiro[5.5]undec-2-en-5-ol

Guidance literature:: With lithium diethylamide; In hexane; at -35 - 20 ℃; for 18h; Yield given. Yields of byproduct given;
DOI:10.1016/S0040-4039(97)00671-0