methyl (2S,3S,4S,6R)-6-{[(4R,5S)-5-[(1R)-1-(benzoyloxy)prop-2-en-1-yl]-2,2-dimethyl-1,3-dioxolan-4-yl]methyl}-3,4-bis(benzyloxy)-5-oxooxane-2-carboxylate

Base Information

Chemical Name:methyl (2S,3S,4S,6R)-6-{[(4R,5S)-5-[(1R)-1-(benzoyloxy)prop-2-en-1-yl]-2,2-dimethyl-1,3-dioxolan-4-yl]methyl}-3,4-bis(benzyloxy)-5-oxooxane-2-carboxylate
CAS No.:1391973-98-0
Molecular Formula:C₃₇H₄₀O₁₀
Molecular Weight:644.719
Hs Code.:

Synonyms:methyl (2S,3S,4S,6R)-6-{[(4R,5S)-5-[(1R)-1-(benzoyloxy)prop-2-en-1-yl]-2,2-dimethyl-1,3-dioxolan-4-yl]methyl}-3,4-bis(benzyloxy)-5-oxooxane-2-carboxylate

Suppliers and Price of methyl (2S,3S,4S,6R)-6-{[(4R,5S)-5-[(1R)-1-(benzoyloxy)prop-2-en-1-yl]-2,2-dimethyl-1,3-dioxolan-4-yl]methyl}-3,4-bis(benzyloxy)-5-oxooxane-2-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of methyl (2S,3S,4S,6R)-6-{[(4R,5S)-5-[(1R)-1-(benzoyloxy)prop-2-en-1-yl]-2,2-dimethyl-1,3-dioxolan-4-yl]methyl}-3,4-bis(benzyloxy)-5-oxooxane-2-carboxylate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of methyl (2S,3S,4S,6R)-6-{[(4R,5S)-5-[(1R)-1-(benzoyloxy)prop-2-en-1-yl]-2,2-dimethyl-1,3-dioxolan-4-yl]methyl}-3,4-bis(benzyloxy)-5-oxooxane-2-carboxylate

There total 11 articles about methyl (2S,3S,4S,6R)-6-{[(4R,5S)-5-[(1R)-1-(benzoyloxy)prop-2-en-1-yl]-2,2-dimethyl-1,3-dioxolan-4-yl]methyl}-3,4-bis(benzyloxy)-5-oxooxane-2-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 1391974-12-1
methyl (2S,3S,4R,5S,6R)-6-{[(4R,5S)-5-[(1R)-1-(benzoyloxy)prop-2-en-1-yl]-2,2-dimethyl-1,3-dioxolan-4-yl]methyl}-3,4-bis(benzyloxy)-5-hydroxyoxane-2-carboxylate

: 1391973-98-0
methyl (2S,3S,4S,6R)-6-{[(4R,5S)-5-[(1R)-1-(benzoyloxy)prop-2-en-1-yl]-2,2-dimethyl-1,3-dioxolan-4-yl]methyl}-3,4-bis(benzyloxy)-5-oxooxane-2-carboxylate

Guidance literature:: With sodium hydrogencarbonate; Dess-Martin periodane; In dichloromethane; at 20 ℃; for 0.666667h; Inert atmosphere;
DOI:10.1002/anie.201201826

Reference yield:

: 1391973-97-9
(1R)-1-[(4S,5R)-5-{[(2R,3S,4R,5R,6R)-4,5-bis(benzyloxy)-3-hydroxy-6-(hydroxymethyl)oxan-2-yl]methyl}-2,2-dimethyl-1,3-dioxolan-4-yl]prop-2-en-1-yl benzoate

: 1391973-98-0
methyl (2S,3S,4S,6R)-6-{[(4R,5S)-5-[(1R)-1-(benzoyloxy)prop-2-en-1-yl]-2,2-dimethyl-1,3-dioxolan-4-yl]methyl}-3,4-bis(benzyloxy)-5-oxooxane-2-carboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene / dichloromethane / 4 h / 20 °C / Inert atmosphere

2: methanol; hexane; toluene / 1 h / 20 °C / Inert atmosphere

3: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 0.67 h / 20 °C / Inert atmosphere

With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene; sodium hydrogencarbonate; Dess-Martin periodane; In methanol; hexane; dichloromethane; toluene;
DOI:10.1002/anie.201201826

Reference yield:

: C₃₆H₄₀O₁₀

: 1391973-98-0
methyl (2S,3S,4S,6R)-6-{[(4R,5S)-5-[(1R)-1-(benzoyloxy)prop-2-en-1-yl]-2,2-dimethyl-1,3-dioxolan-4-yl]methyl}-3,4-bis(benzyloxy)-5-oxooxane-2-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: methanol; hexane; toluene / 1 h / 20 °C / Inert atmosphere

2: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 0.67 h / 20 °C / Inert atmosphere

With sodium hydrogencarbonate; Dess-Martin periodane; In methanol; hexane; dichloromethane; toluene;
DOI:10.1002/anie.201201826