2-acetyl-3-phenyl-1a,2,3,7a-tetrahydrocyclopropisoquinoline

Base Information

Chemical Name:2-acetyl-3-phenyl-1a,2,3,7a-tetrahydrocyclopropisoquinoline
CAS No.:104576-41-2
Molecular Formula:C₁₈H₁₇NO
Molecular Weight:263.339
Hs Code.:

2-acetyl-3-phenyl-1a,2,3,7a-tetrahydrocycloprop<c>isoquinoline

Synonyms:2-acetyl-3-phenyl-1a,2,3,7a-tetrahydrocyclopropisoquinoline

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-acetyl-3-phenyl-1a,2,3,7a-tetrahydrocyclopropisoquinoline

Chemical Property:

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Technology Process of 2-acetyl-3-phenyl-1a,2,3,7a-tetrahydrocyclopropisoquinoline

There total 4 articles about 2-acetyl-3-phenyl-1a,2,3,7a-tetrahydrocyclopropisoquinoline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: 104576-36-5
2-acetyl-1,1-dibromo-3-phenyl-1a,2,3,7b-tetrahydro-1H-cyclopropisoquinoline

: 104576-41-2
2-acetyl-3-phenyl-1a,2,3,7a-tetrahydrocyclopropisoquinoline

Guidance literature:: With tri-n-butyl-tin hydride; In toluene; for 28h; Heating; Irradiation;
DOI:10.1021/jo00372a009

Reference yield:

: 52250-50-7
1-phenyl-3,4-dihydroisoquinoline

: 104576-41-2
2-acetyl-3-phenyl-1a,2,3,7a-tetrahydrocyclopropisoquinoline

Guidance literature:: Multi-step reaction with 3 steps

1: 63 percent / AcOK / 6 h / Heating

2: 60 percent / 40percent aq. NaOH / benzyltriethyl ammonium chloride / 4.5 h

3: 50 percent / tributyltin hydride / toluene / 28 h / Heating; Irradiation

With sodium hydroxide; tri-n-butyl-tin hydride; potassium acetate; N-benzyl-N,N,N-triethylammonium chloride; In toluene;
DOI:10.1021/jo00372a009

Reference yield:

: 3278-14-6
N-phenethylbenzamide

: 104576-41-2
2-acetyl-3-phenyl-1a,2,3,7a-tetrahydrocyclopropisoquinoline

Guidance literature:: Multi-step reaction with 4 steps

1: 90 percent / P₂O₅, POCl₃ / xylene / 3 h / Heating

2: 63 percent / AcOK / 6 h / Heating

3: 60 percent / 40percent aq. NaOH / benzyltriethyl ammonium chloride / 4.5 h

4: 50 percent / tributyltin hydride / toluene / 28 h / Heating; Irradiation

With sodium hydroxide; tri-n-butyl-tin hydride; potassium acetate; phosphorus pentoxide; trichlorophosphate; N-benzyl-N,N,N-triethylammonium chloride; In toluene; xylene;
DOI:10.1021/jo00372a009