(E)-(R)-1-[(1-iodo-2-methylhepta-1,6-dien-4-yloxy)methyl]-4-methoxybenzene

Base Information

Chemical Name:(E)-(R)-1-[(1-iodo-2-methylhepta-1,6-dien-4-yloxy)methyl]-4-methoxybenzene
CAS No.:936445-65-7
Molecular Formula:C₁₆H₂₁IO₂
Molecular Weight:372.246
Hs Code.:

Synonyms:(E)-(R)-1-[(1-iodo-2-methylhepta-1,6-dien-4-yloxy)methyl]-4-methoxybenzene

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Chemical Property of (E)-(R)-1-[(1-iodo-2-methylhepta-1,6-dien-4-yloxy)methyl]-4-methoxybenzene

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Technology Process of (E)-(R)-1-[(1-iodo-2-methylhepta-1,6-dien-4-yloxy)methyl]-4-methoxybenzene

There total 3 articles about (E)-(R)-1-[(1-iodo-2-methylhepta-1,6-dien-4-yloxy)methyl]-4-methoxybenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 936445-64-6
(E)-(R)-1-iodo-2-methylhepta-1,6-dien-4-ol

: 89238-99-3
O-(4-methoxybenzyl)-trichloroacetimidate

: 936445-65-7
(E)-(R)-1-[(1-iodo-2-methylhepta-1,6-dien-4-yloxy)methyl]-4-methoxybenzene

Guidance literature:: With camphor-10-sulfonic acid; In dichloromethane; at 20 ℃; for 12h; Inert atmosphere;
DOI:10.1021/jo900945x

Reference yield:

: 78592-73-1
(E)-4-iodo-3-methylbut-3-en-1-ol

: 936445-65-7
(E)-(R)-1-[(1-iodo-2-methylhepta-1,6-dien-4-yloxy)methyl]-4-methoxybenzene

Guidance literature:: Multi-step reaction with 3 steps

1.1: Dess-Martin periodinane / CH₂Cl₂ / 0 - 20 °C

2.1: chiral cyclopentadienyl(dialkoxy)titanium chloride / diethyl ether; tetrahydrofuran / 2 h / 0 °C

2.2: diethyl ether; tetrahydrofuran / 4 h / -78 °C

3.1: camphorsulfonic acid / CH₂Cl₂ / 12 h / 20 °C

With camphor-10-sulfonic acid; Dess-Martin periodane; In tetrahydrofuran; diethyl ether; dichloromethane; 1.1: Dess-Martin oxidation;
DOI:10.1021/ol070240k

Reference yield:

: 936445-63-5
(E)-4-iodo-3-methylbut-3-enal

: 936445-65-7
(E)-(R)-1-[(1-iodo-2-methylhepta-1,6-dien-4-yloxy)methyl]-4-methoxybenzene

Guidance literature:: Multi-step reaction with 2 steps

1.1: chiral cyclopentadienyl(dialkoxy)titanium chloride / diethyl ether; tetrahydrofuran / 2 h / 0 °C

1.2: diethyl ether; tetrahydrofuran / 4 h / -78 °C

2.1: camphorsulfonic acid / CH₂Cl₂ / 12 h / 20 °C

With camphor-10-sulfonic acid; In tetrahydrofuran; diethyl ether; dichloromethane;
DOI:10.1021/ol070240k