N-(2-hydroxyl-3,5-di-tert-butylbenzaldehyde)-1-amino-2-benzeneimine

Base Information

• Chemical Name: N-(2-hydroxyl-3,5-di-tert-butylbenzaldehyde)-1-amino-2-benzeneimine
• CAS No.: 308086-87-5
• Molecular Formula: C₂₁H₂₈N₂O
• Molecular Weight: 324.466
• Mol file: 308086-87-5.mol

Synonyms:N-(2-hydroxyl-3,5-di-tert-butylbenzaldehyde)-1-amino-2-benzeneimine

Chemical Property of N-(2-hydroxyl-3,5-di-tert-butylbenzaldehyde)-1-amino-2-benzeneimine

Chemical Property:

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-(2-hydroxyl-3,5-di-tert-butylbenzaldehyde)-1-amino-2-benzeneimine

There total 1 articles about N-(2-hydroxyl-3,5-di-tert-butylbenzaldehyde)-1-amino-2-benzeneimine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

3,5-di-tert-butyl-2-hydroxybenzaldehyde (37942-07-7) + 1,2-diamino-benzene (95-54-5) → N-(2-hydroxyl-3,5-di-tert-butylbenzaldehyde)-1-amino-2-benzeneimine (308086-87-5)

Guidance literature:

With toluene-4-sulfonic acid; In ethanol; for 12h; Inert atmosphere; Reflux;

DOI:10.1021/acs.organomet.7b00106

Reference yield: 95.0%

3,5-Dibromosalicylaldehyde (90-59-5) + N-(2-hydroxyl-3,5-di-tert-butylbenzaldehyde)-1-amino-2-benzeneimine (308086-87-5) → C28H30Br2N2O2

Guidance literature:

With toluene-4-sulfonic acid; In ethanol; at 25 ℃; for 1h; Inert atmosphere;

DOI:10.1021/acs.organomet.7b00106

Reference yield: 95.0%

N-(2-hydroxyl-3,5-di-tert-butylbenzaldehyde)-1-amino-2-benzeneimine (308086-87-5) + diethylaluminium chloride (96-10-6) → ((C4H9)2OC6H2CHNC6H4NH2)2AlCl (308086-82-0,308086-80-8)

Guidance literature:

In toluene; byproducts: C2H6; a soln. of (C2H5)2AlCl in toluene was added at room temp. to a stirred soln. of salicilidene compound in toluene, the soln. was stirred for 5 h(inert atm.); solvent was removed, the solid was washed with hexane, dried under vac.; elem. anal.;

DOI:10.1021/om000058m

upstream raw materials:

3,5-di-tert-butyl-2-hydroxybenzaldehyde

1,2-diamino-benzene

Downstream raw materials:

(C₄H₉)2OC₆H₂CHNC₆H₄NH₂Ga(CH₃)2

((C₄H₉)2OC₆H₂CHNC₆H₄NH₂)2AlCl

(C₄H₉)2OC₆H₂CHNC₆H₄NH₂Ga(CH₃)Cl

C₄₃H₄₂N₂O₃