Diethylaluminum chloride

Base Information

• Chemical Name: Diethylaluminum chloride
• CAS No.: 96-10-6
• Deprecated CAS: 12080-90-9
• Molecular Formula: C4H10AlCl
• Molecular Weight: 120.558
• Hs Code.: 2931.00
• European Community (EC) Number: 202-477-2
• UN Number: 3052
• UNII: 9J9260380K
• DSSTox Substance ID: DTXSID5026592
• Wikipedia: Diethylaluminium_chloride
• Wikidata: Q413029
• Mol file: 96-10-6.mol

Synonyms:Diethylaluminum chloride;Aluminum, chlorodiethyl-;96-10-6;Diethylaluminium chloride;CHLORODIETHYLALUMINUM;Diethylchloroaluminum;Diethylaluminum monochloride;Aluminum diethyl monochloride;DEAK;chloro(diethyl)alumane;Aluminum, dichlorotetraethyldi-;HSDB 5299;EINECS 202-477-2;UNII-9J9260380K;chloro(diethyl)aluminum;9J9260380K;EC 202-477-2;chlorodiethylalumane;Aluminio, clorodietil-;C4H10AlCl;chloranyl(diethyl)alumane;Aluminium, chlorodiethyl-;Chloro(diethyl)aluminium #;C4-H10-Al-Cl;Diethylaluminum chloride, 97%;deak (diethylaluminum chloride);DTXSID5026592;PARAROSANILINEHYDROCHLORIDE;DIETHYLCHLOROALUMINUM [HSDB];MFCD00000459;AKOS009156943;UN 1101;LS-16469;FT-0656865;EN300-53329;Chlorodiethylaluminum;(Diethylaluminum chloride);A845545;Q413029

Chemical Property of Diethylaluminum chloride

Chemical Property:

• Appearance/Colour: colorless liquid
• Vapor Pressure: 3 mmHg ( 60 °C)
• Melting Point: -85°C
• Boiling Point: 125°C 50mm
• Flash Point: ?9°F
• PSA: 0.00000
• Density: 0.887g/mLat 25°C
• LogP: 2.63730
• Storage Temp.: 0-6°C
• Sensitive.: Air & Moisture Sensitive
• Solubility.: Miscible with hexane.
• Water Solubility.: reac H2O [CRC10]
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 120.0286414
• Heavy Atom Count: 6
• Complexity: 26.7

Purity/Quality:

99% ^*data from raw suppliers

DiethylaluminumChloride-25%inToluene(about2M) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F,C,N
• Hazard Codes: F,C,N
• Statements: 14-17-34-67-65-62-51/53-48/20-14/15-11-63-50/53
• Safety Statements: 36/37/39-45-62-61-43-26-16

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Metals, Organic Compounds
• Canonical SMILES: CC[Al](CC)Cl

Technology Process of Diethylaluminum chloride

There total 18 articles about Diethylaluminum chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.4%

triethylaluminum (97-93-8) → diethylaluminium chloride (96-10-6)

Guidance literature:

aluminium trichloride;

Reference yield:

chloroform (67-66-3,8013-54-5) + triethylaluminum (97-93-8) → ethane (74-84-0) + ethene (74-85-1) + 1,1,1-trichloropropane (7789-89-1) + diethylaluminium chloride (96-10-6)

Guidance literature:

With bis(acetylacetonate)nickel(II); In cyclohexane; at 20 ℃; Further byproducts given;

DOI:10.1007/BF02494653

Reference yield:

triethylaluminum (97-93-8) + zinc(II) chloride (7646-85-7,24359-56-6) → diethylzinc (557-20-0) + diethylaluminium chloride (96-10-6)

Guidance literature:

In liquid paraffin; at 36 - 40 ℃; for 12h; Product distribution / selectivity; Inert atmosphere; Industry scale;

upstream raw materials:

triethylaluminum

chloroform

chloroethane

germaniumtetrachloride

Downstream raw materials:

4,4-Diphenyl-hexansaeure

1-(phenylthio)-2-butanone

2-ethyl-1-hexene

di(n-hexyl)aluminum chloride

Refernces

β-Diketiminato 3d-metal compounds: Synthesis, characterization and catalytic behavior towards ethylene

10.1016/j.ica.2011.01.063

This research study on the synthesis, characterization, and catalytic behavior of β-diketiminate 3d-metal compounds towards ethylene oligomerization and polymerization. The purpose of the study was to explore the physical properties of 1,5-diazapentadienyls (β-diketiminates) and their use as ancillary ligands in transition metal chemistry, with a focus on understanding the formation mechanism of mononuclear, dinuclear, and trinuclear complexes. The researchers synthesized a series of metal compounds (2–7) by reacting a nonsymmetric β-diketiminato lithium complex (1c) with various 3d-metal (II) chlorides. The synthesized compounds were fully characterized using elemental analysis, spectroscopic analyses, and single-crystal X-ray diffraction. The catalytic behavior of these compounds was evaluated using methylaluminoxane (MAO) or diethylaluminum chloride (Et2AlCl) as cocatalysts.