methyl 5-<<3-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-propenoyl>amino>-2,4-pentadienoate

Base Information

• Chemical Name: methyl 5-<<3-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-propenoyl>amino>-2,4-pentadienoate
• CAS No.: 162793-04-6
• Molecular Formula: C₁₈H₂₅NO₃
• Molecular Weight: 303.401
• Mol file: 162793-04-6.mol

Synonyms:methyl 5-<<3-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-propenoyl>amino>-2,4-pentadienoate

Chemical Property of methyl 5-<<3-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-propenoyl>amino>-2,4-pentadienoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl 5-<<3-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-propenoyl>amino>-2,4-pentadienoate

There total 2 articles about methyl 5-<<3-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-propenoyl>amino>-2,4-pentadienoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

methyl 5-amino>-2,4-pentadienoate → methyl 5-<<3-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-propenoyl>amino>-2,4-pentadienoate (162793-04-6)

Guidance literature:

With lithium iodide; In N,N-dimethyl-formamide; for 8h; Heating;

DOI:10.1248/cpb.43.100

Reference yield:

(E)-3-(2,6,6-trimethylcyclohex-1-en-1-yl)acryloyl chloride (69258-08-8) + methyl 5-(methoxycarbonylamino)-2,4-pentadienoate → methyl 5-<<3-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-propenoyl>amino>-2,4-pentadienoate (162793-04-6) + methyl 5-amino>-2,4-pentadienoate

Guidance literature:

With sodium hydride; Yield given. Multistep reaction. Yields of byproduct given; 1.) DMF, 0 deg C, 2.) DMF, benzene, 0 deg C, 1 h;

DOI:10.1248/cpb.43.100

Reference yield: 67.0%

methyl 5-<<3-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-propenoyl>amino>-2,4-pentadienoate (162793-04-6) → 5-<<3-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-propenoyl>amino>-2,4-pentadienoic acid

Guidance literature:

With sodium hydroxide; In methanol;

DOI:10.1248/cpb.43.100

upstream raw materials:

(E)-3-(2,6,6-trimethylcyclohex-1-en-1-yl)acryloyl chloride