[Pd(2-phenylimidazole)₂Cl₂]

Base Information

• Chemical Name: [Pd(2-phenylimidazole)₂Cl₂]
• CAS No.: 1040403-31-3
• Molecular Formula: C₁₈H₁₆Cl₂N₄Pd
• Molecular Weight: 465.678
• Mol file: 1040403-31-3.mol

Synonyms:[Pd(2-phenylimidazole)₂Cl₂]

Chemical Property of [Pd(2-phenylimidazole)₂Cl₂]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Pd(2-phenylimidazole)₂Cl₂]

There total 3 articles about [Pd(2-phenylimidazole)₂Cl₂] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

2-Phenylimidazole (670-96-2) + palladium dichloride → dichlorobis(2-phenyl-1H-imidazole)palladium(II) (1040403-31-3)

Guidance literature:

In N,N-dimethyl-formamide; to a suspn. of PdCl2 in DMF was added 2-phenylimidazole under Ar, the mixt. was stirred at 50°C for 2 h; the soln. was diluted with DMF, toluene was added, ppt. was filtered, washed with toluene and dried in air; elem. anal.;

DOI:10.1021/om800230y

Reference yield: 50.0%

2-Phenylimidazole (670-96-2) + palladium dichloride → [Pd(2-phenylimidazole)2Cl2] (1040403-31-3)

Guidance literature:

In acetonitrile; CH3CN added to PdCl2, heated for 30 min at 70 °C, 2-phenylimidazole added, heating continued for 1.5 h; cooled, filtered, washed with CH3CN, dried in vac.; elem. anal.;

DOI:10.1016/j.ica.2010.08.037

Reference yield:

2-Phenylimidazole (670-96-2) + potassium tetrachloropalladate(II) (10025-98-6) → [Pd(2-phenylimidazole)2Cl2] (1040403-31-3)

Guidance literature:

In methanol; water; acetonitrile; for 1h;

DOI:10.1016/j.poly.2018.12.021

upstream raw materials:

2-Phenylimidazole

potassium tetrachloropalladate(II)

Refernces

• 1、 Sadaf, Haseeba,Imtiaz-ud-Din,Zahra, Syeda Saniya,Ihsan-ul-Haq,Nadeem, Shafqat,Tahir, Muhammad Nawaz,Ahmad, Saeed,Andleeb, Sohaila. "Synthesis, X-ray structures and biological properties of palladium(II) complexes of 1,2-dimethylimidazole and benzimidazole". . p. 101 - 107. Retrieved 2019/01/08.