Re(N-2,6-C₆H₃Me₂)3(CH₂t-Bu)

Base Information

Chemical Name:Re(N-2,6-C₆H₃Me₂)3(CH₂t-Bu)
CAS No.:118968-29-9
Molecular Formula:C₂₉H₃₈N₃Re
Molecular Weight:614.848
Hs Code.:

Re(N-2,6-C<sub>6</sub>H<sub>3</sub>Me<sub>2</sub>)3(CH<sub>2</sub>t-Bu)

Synonyms:Re(N-2,6-C₆H₃Me₂)3(CH₂t-Bu)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Re(N-2,6-C₆H₃Me₂)3(CH₂t-Bu)

Chemical Property:

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Safty Information:

Pictogram(s):
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MSDS Files:: SDS file from LookChem

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Technology Process of Re(N-2,6-C₆H₃Me₂)3(CH₂t-Bu)

There total 2 articles about Re(N-2,6-C₆H₃Me₂)3(CH₂t-Bu) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 118968-23-3
Re(N-2,6-C₆H₃Me₂)3Cl

: 13132-23-5
2,2-dimethylpropylmagnesium chloride

: 118968-29-9
Re(N-2,6-C₆H₃Me₂)3(CH₂t-Bu)

Guidance literature:: In diethyl ether; byproducts: MgCl2; addn. of t-BuCH2MgCl in ether to a soln. of Re-compd. in ether at -40°C, stirred for 48 h at 25°C; filtered through Celite (removal of MgCl2), taken to dryness, extn. (pentane), filtered through Celite, concd., cooled, recrystn. (pentane); elem. anal.;
DOI:10.1016/S0277-5387(00)80695-6

Reference yield:

: 118968-19-7
Re(N-2,6-C₆H₃Me₂)2(CH₂t-Bu)Cl₂

: 6674-22-2,83329-50-4
1,8-diazabicyclo[5.4.0]undec-7-ene

: {DBUH}{Re(N-2,6-C₆H₃Me₂)2(Ct-Bu)Cl₃}

: 118968-29-9
Re(N-2,6-C₆H₃Me₂)3(CH₂t-Bu)

: 78204-84-9
1,8-diazabicyclo<5.4.0>undec-7-ene hidrochloride

Guidance literature:: In benzene-d6; 5°C; detn. by (1)H-NMR, Re product ratio 1:1;
DOI:10.1016/S0277-5387(00)80695-6

Reference yield: 78.0%

: 118968-29-9
Re(N-2,6-C₆H₃Me₂)3(CH₂t-Bu)

: 118968-20-0
Re(N-2,6-C₆H₃Cl₂)2(CH₂t-Bu)Cl₂

: 33663-43-3
2,6-dichloroaniline hydrochloride

Guidance literature:: With hydrogenchloride; In diethyl ether; dichloromethane; addn. of HCl gas to a soln. of Re-compd. in CH2Cl2 and ether at -78°C, kept at -78°C for 20 min, warmed to 25°C over 45 min; filtered through Celite, concd., cooled, recrystn. from a mixture of ether and pentane; elem. anal.;
DOI:10.1016/S0277-5387(00)80695-6