Ru{C≡CC(CN)=C(CN)₂}(dppe)Cp*

Base Information

• Chemical Name: Ru{C≡CC(CN)=C(CN)₂}(dppe)Cp*
• CAS No.: 1112299-03-2
• Molecular Formula: C₄₃H₃₉N₃P₂Ru
• Molecular Weight: 760.82
• Mol file: 1112299-03-2.mol

Synonyms:Ru{C≡CC(CN)=C(CN)₂}(dppe)Cp*

Chemical Property of Ru{C≡CC(CN)=C(CN)₂}(dppe)Cp*

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ru{C≡CC(CN)=C(CN)₂}(dppe)Cp*

There total 2 articles about Ru{C≡CC(CN)=C(CN)₂}(dppe)Cp* which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

[Ru(=C=CH2)(1,2-bis(diphenylphosphino)ethane)Cp*]PF6 (583884-55-3) + ethenetetracarbonitrile (670-54-2) → Ru{C≡CC(CN)=C(CN)2}(dppe)Cp* (1112299-03-2)

Guidance literature:

With CH₃Li; In tetrahydrofuran; hexane; (N2) a soln. of complex in THF at -78°C was treated with CH3Li inhexane, after 25 min tetracyanoethene was added, warmed to room temp., stirred overnight; the solvent was removed, preparative TLC; elem. anal.;

DOI:10.1021/om2007503

Reference yield: 93.0%

(pentamethylcyclopentadienyl)(1,2-bis(diphenylphosphino)ethane)RuC2H (583884-57-5) + ethenetetracarbonitrile (670-54-2) → Ru{C≡CC(CN)=C(CN)2}(dppe)Cp* (1112299-03-2)

Guidance literature:

In not given; byproducts: HCN;

DOI:10.1039/b810720c

Reference yield: 89.0%

tetrafluoroboric acid diethyl ether (67969-82-8) + Ru{C≡CC(CN)=C(CN)2}(dppe)Cp* (1112299-03-2) → [Ru(=C=CHC(CN)=C(CN)2)(dppe)(η5-C5Me5)]BF4

Guidance literature:

In dichloromethane; (N2) CH2Cl2-soln. of complex was treated with HBF4*C2H5OC2H5, stirred for 3 min; solvent was removed, the residue was taken up in CH2Cl2 and added to hexane; elem. anal.;

DOI:10.1021/om2007503

upstream raw materials:

(pentamethylcyclopentadienyl)(1,2-bis(diphenylphosphino)ethane)RuC₂H

ethenetetracarbonitrile

[Ru(=C=CH₂)(1,2-bis(diphenylphosphino)ethane)Cp*]PF₆

Downstream raw materials:

Ru(C2C(OMe)=C(CN)2)(dppe)(η5-pentamethylcyclopentadienyl)

Ru(CCC(OBut)=C(CN)2)(dppe)(η5-C5Me5)

Ru(CCC[P(O)Ph2]=C(CN)2)(dppe)(η5-C5Me5)*CH2Cl2

Ru(CCC(NHEt)=C(CN)2)(dppe)(η5-C5Me5)