4,6-Dideoxyhexopyranose

Base Information

• Chemical Name: 4,6-Dideoxyhexopyranose
• CAS No.: 29325-32-4
• Molecular Formula: C6H12 O4
• Molecular Weight: 148.1571
• NSC Number: 170208
• DSSTox Substance ID: DTXSID60951882
• Mol file: 29325-32-4.mol

Synonyms:29325-32-4;4,6-didesoxyhexose;4,6-dideoxyhexopyranose;SCHEMBL2534531;DTXSID60951882;NSC170208;NSC-170208;PD043100;FT-0665817

Chemical Property of 4,6-Dideoxyhexopyranose

Chemical Property:

• Vapor Pressure: 0.000435mmHg at 25°C
• Boiling Point: 281°C at 760 mmHg
• Flash Point: 123.8°C
• Density: 1.366g/cm³
• XLogP3: -1.1
• Hydrogen Bond Donor Count: 3
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 148.07355886
• Heavy Atom Count: 10
• Complexity: 116

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1CC(C(C(O1)O)O)O

Technology Process of 4,6-Dideoxyhexopyranose

There total 18 articles about 4,6-Dideoxyhexopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

methyl 4,6-dideoxy-α-D-arabino-hexopyranoside (55338-33-5) → D-arabino-4,6-dideoxy-hexose (22435-60-5,23583-37-1,29325-32-4,33302-99-7,66900-21-8,116907-46-1,116907-47-2,132957-12-1,132957-13-2,1279230-33-9)

Guidance literature:

With Dowex-50W(H⁺); In water; for 8.5h; Heating;

DOI:10.1246/bcsj.66.523

Reference yield: 93.0%

1,2,3-tri-O-benzoyl-4,6-dideoxy-α-L-xylo-hexopyranose (132867-80-2) → 4-deoxy-L-fucose (22435-60-5,23583-37-1,29325-32-4,33302-99-7,66900-21-8,116907-46-1,116907-47-2,132957-12-1,132957-13-2,1279230-33-9)

Guidance literature:

With sodium methylate; In methanol; for 0.5h; Ambient temperature;

DOI:10.1016/0008-6215(91)80150-L

Reference yield: 84.0%

methyl 4,6-dideoxy-α-D-glucopyranoside (20585-18-6) → D-xylo-4,6-dideoxy-hexose (29325-32-4,1279230-33-9)

Guidance literature:

With Dowex-50W (H+); water; for 8.5h; Heating;

DOI:10.1016/S0040-4039(00)79484-6

upstream raw materials:

methyl 4,6-dideoxy-α-D-arabino-hexopyranoside

D-chalcose

methyl 4,6-dideoxy-α-D-glucopyranoside

2-O-Benzoyl-4,6-didesoxy-D-xylo-hexose

Downstream raw materials:

(E)-3-[(4R,5R)-5-((R)-2-Hydroxy-propyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-acrylic acid 2-(toluene-4-sulfonyl)-ethyl ester

(E)-(4S,5S,7R)-4,5,7-Trihydroxy-oct-2-enoic acid 2-(toluene-4-sulfonyl)-ethyl ester

2-(p-tolylsulfonyl)ethyl (2E,4R,5R,7R)-4,5,7-trihydroxy-2-octenoate

p-toluenesulfonylethyl (4R,5R,7R,2E)-7-hydroxy-4,5-dimethylmethylenedioxy-2-octenoate

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