C₄₈H₈₁N₉

Base Information

• Chemical Name: C₄₈H₈₁N₉
• CAS No.: 1313742-89-0
• Molecular Formula: C₄₈H₈₁N₉
• Molecular Weight: 784.231
• Mol file: 1313742-89-0.mol

Synonyms:C₄₈H₈₁N₉

Chemical Property of C₄₈H₈₁N₉

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of C₄₈H₈₁N₉

There total 4 articles about C₄₈H₈₁N₉ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.92%

dodecyl azide (13733-78-3) + 1,3,5-Triethynylbenzene (7567-63-7) → C48H81N9 (1313742-89-0)

Guidance literature:

With copper(ll) sulfate pentahydrate; sodium L-ascorbate; In tetrahydrofuran; water; at 20 ℃; for 12h;

DOI:10.1039/c7tc01039g

Reference yield:

1,3,5-trisbromobenzene (626-39-1) → C48H81N9 (1313742-89-0)

Guidance literature:

Multi-step reaction with 3 steps

1: pyridine; copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; triethylamine / 12 h / 90 °C / Inert atmosphere

2: potassium carbonate / tetrahydrofuran; methanol / 3 h / Inert atmosphere

3: copper(ll) sulfate pentahydrate; sodium L-ascorbate / tetrahydrofuran; water / 12 h / 20 °C

With pyridine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; copper(ll) sulfate pentahydrate; potassium carbonate; sodium L-ascorbate; triethylamine; In tetrahydrofuran; methanol; water;

DOI:10.1002/anie.201101013

Reference yield:

1-dodecylbromide (143-15-7) → C48H81N9 (1313742-89-0)

Guidance literature:

Multi-step reaction with 2 steps

1: sodium azide / N,N-dimethyl-formamide / 48 h / 100 °C / Inert atmosphere

2: copper(ll) sulfate pentahydrate; sodium L-ascorbate / tetrahydrofuran; water / 12 h / 20 °C

With sodium azide; copper(ll) sulfate pentahydrate; sodium L-ascorbate; In tetrahydrofuran; water; N,N-dimethyl-formamide;

DOI:10.1002/anie.201101013

upstream raw materials:

dodecyl azide

1,3,5-Triethynylbenzene

1,3,5-trisbromobenzene

1-dodecylbromide