O-tosyl-N-trichloroethoxycarbonylhydroxylamine

Base Information

• Chemical Name: O-tosyl-N-trichloroethoxycarbonylhydroxylamine
• CAS No.: 931109-52-3
• Molecular Formula: C₁₀H₁₀Cl₃NO₅S
• Molecular Weight: 362.618
• Mol file: 931109-52-3.mol

Synonyms:O-tosyl-N-trichloroethoxycarbonylhydroxylamine

Chemical Property of O-tosyl-N-trichloroethoxycarbonylhydroxylamine

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of O-tosyl-N-trichloroethoxycarbonylhydroxylamine

There total 1 articles about O-tosyl-N-trichloroethoxycarbonylhydroxylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

2,2,2-trichloroethyl N-hydroxycarbamate (99027-85-7) + p-toluenesulfonyl chloride (98-59-9) → O-tosyl-N-trichloroethoxycarbonylhydroxylamine (931109-52-3)

Guidance literature:

With triethylamine; In diethyl ether; at 0 - 20 ℃;

DOI:10.1021/jo301372y

Reference yield: 92.0%

O-tosyl-N-trichloroethoxycarbonylhydroxylamine (931109-52-3) + cyclohexane (110-82-7,25012-93-5) → 2,2,2-trichloroethyl N-cyclohexylcarbamate (874394-02-2)

Guidance literature:

With potassium carbonate; dirhodium(II) tetrakis(triphenylacetate); In 1,1,2,2-tetrachloroethane; at 25 ℃;

DOI:10.1021/ol062953t

Reference yield: 75.0%

O-tosyl-N-trichloroethoxycarbonylhydroxylamine (931109-52-3) + 4-chloro-N,N-dimethylaniline (698-69-1) → 2,2,2-trichloroethyl (((4-chlorophenyl)(methyl)amino)methyl)carbamate

Guidance literature:

With C₁₄H₃₃O₂Rh₂; potassium carbonate; In toluene; at 20 ℃; for 12h; chemoselective reaction;

DOI:10.1055/a-1334-6450

upstream raw materials:

2,2,2-trichloroethyl N-hydroxycarbamate

p-toluenesulfonyl chloride

Downstream raw materials:

2,2,2-trichloroethyl N-cyclohexylcarbamate

β,β,β-Trichloroethyl Benzylaminoformate