C₅₀H₃₁N₅Ni

Base Information

• Chemical Name: C₅₀H₃₁N₅Ni
• CAS No.: 1345888-88-1
• Molecular Formula: C₅₀H₃₁N₅Ni
• Molecular Weight: 760.52
• Mol file: 1345888-88-1.mol

Synonyms:C₅₀H₃₁N₅Ni

Chemical Property of C₅₀H₃₁N₅Ni

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₅₀H₃₁N₅Ni

There total 5 articles about C₅₀H₃₁N₅Ni which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

(2-phenylamino-5,10,15,20-tetraphenylporphyrinato)nickel(II) (1058186-88-1) → C50H31N5Ni (1345888-88-1)

Guidance literature:

In nitrobenzene; for 19h; Reflux;

DOI:10.1142/S108842461100346X

Reference yield: 66.0%

iodobenzene (591-50-4) + [Ni(C20H7N4(C6H5)3(C6H4NH))] (650598-88-2) → C50H31N5Ni (1345888-88-1)

Guidance literature:

With copper(l) iodide; potassium carbonate; L-proline; In dimethyl sulfoxide; at 90 ℃; for 4h;

DOI:10.1142/S108842461100346X

Reference yield:

nickel(II) 2-nitro-5,10,15,20-tetraphenylporphyrinate (95212-88-7) → C50H31N5Ni (1345888-88-1)

Guidance literature:

Multi-step reaction with 3 steps

1: hydrogenchloride; tin / chloroform; water / 20 °C

2: potassium tert-butylate; palladium diacetate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl / toluene / 100 °C / Inert atmosphere

3: nitrobenzene / 19 h / Reflux

With hydrogenchloride; tin; potassium tert-butylate; palladium diacetate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; In chloroform; water; nitrobenzene; toluene; 2: Buchwald-Hartwig amination;

DOI:10.1142/S108842461100346X

upstream raw materials:

(2-phenylamino-5,10,15,20-tetraphenylporphyrinato)nickel(II)

(2-amino-5,10,15,20-tetraphenylporphyrinato)-nickel(II)

nickel(II) 2-nitro-5,10,15,20-tetraphenylporphyrinate

iodobenzene

Downstream raw materials:

C₅₀H₃₁CuN₅